AB-alternating copolymers via chain-growth polymerization: synthesis, characterization, self-assembly, and functions

K Nishimori, M Ouchi - Chemical Communications, 2020 - pubs.rsc.org
An AB-alternating copolymer is distinctly unique in comparison with other copolymers (eg,
random, gradient, and block) because the structure is uniform in terms of sequence: there is …

Orthogonal multiple click reactions in synthetic polymer chemistry

U Tunca - Journal of Polymer Science Part A: Polymer …, 2014 - Wiley Online Library
This review highlights the concept of multiple click reaction strategy which is utilized for
design and synthesis of well‐defined complex macromolecular structures as well as …

The para-fluoro-thiol reaction as an efficient tool in polymer chemistry

G Delaittre, L Barner - Polymer Chemistry, 2018 - pubs.rsc.org
In the current contribution, we discuss the application and potential of the versatile para-
fluoro-thiol reaction in the context of synthesis and modification of polymers and materials …

An emerging post‐polymerization modification technique: The promise of thiol‐para‐fluoro click reaction

S Agar, E Baysak, G Hizal, U Tunca… - Journal of Polymer …, 2018 - Wiley Online Library
Post‐polymerization modification (PPM) of polymers is extremely beneficial in terms of
designing brand new synthetic pathways toward functional complex polymers. Fortunately …

A General Strategy to Access Alternating Styrene/Substituted Styrene Copolymers by Using a Traceless Controlling Group

Y Xiao, Y Sun, X Wang, Y Xu… - Angewandte Chemie …, 2023 - Wiley Online Library
We herein report a synthetic strategy for alternating copolymers of styrene and substituted
styrenes by utilizing α‐styryl boronate pinacol ester (StBpin) as the co‐monomer through …

Azide–para-Fluoro Substitution on Polymers: Multipurpose Precursors for Efficient Sequential Postpolymerization Modification

JM Noy, Y Li, W Smolan, PJ Roth - Macromolecules, 2019 - ACS Publications
The 2, 3, 4, 5, 6-pentafluorobenzyl group has become a popular reactive functionality in
polymer chemistry because of its high susceptibility to para-fluoro substitution with thiols …

β-Triketones as Reactive Handles for Polymer Diversification via Dynamic Catalyst-Free Diketoenamine Click Chemistry

L Trachsel, KA Stewart, D Konar… - Journal of the …, 2024 - ACS Publications
The spontaneous condensation of amines with β-triketones (TK), forming β, β′-
diketoenamines (DKE) and releasing water as the sole byproduct, exhibits many of the …

Recent developments in the synthesis of sequence controlled polymers

C Qu, J He - Science China Chemistry, 2015 - Springer
The synthesis of sequence controlled polymers received increasing interest in polymer
science. This mini review focuses on the principle and methods developed to control the …

Influence of intramolecular crosslinking on gelation in living copolymerization of monomer and divinyl cross-linker. Monte Carlo simulation studies

P Polanowski, JK Jeszka, K Krysiak, K Matyjaszewski - Polymer, 2015 - Elsevier
The effect of intramolecular crosslinking (IC)(cyclization) on gelation was studied using
Monte Carlo simulations. The consumption of crosslinker in the IC process is proposed as …

Photo-crosslinked polymer cubosomes as a recyclable nanoreactor in organic solvents

JH Kwon, J Kim, KT Kim - Polymer Chemistry, 2021 - pubs.rsc.org
Polymer cubosomes are an emerging class of mesoporous structures formed by the solution
self-assembly of block copolymers (BCPs) with a highly asymmetric block ratio. The internal …