Direct functionalization of (hetero) aromatic C–H bonds has recently emerged as a powerful
tool for the functionalization of organic molecules. In the past decade, while many efforts …

Easy does it: The unique properties of benziodoxolone alkynyl periodinane 1 and gold
catalysts have allowed the development of a high yielding, operationally simple (room …

Silicon–nitrogen bond formation is an important subfield in main group chemistry, and
catalysis is an attractive route for efficient, selective formation of these bonds. Indeed …

Transition-metal-catalyzed carbene transformations are one of the most powerful reactions
in organic chemistry.[1] Transition-metal catalysts have played a crucial role in modulating …

A base-free, catalytic protocol for the dehydrogenative Si–N coupling of weakly nucleophilic
N–H groups of heteroarenes or aryl-substituted amines with equimolar amounts of …

1, 5-Diazabicyclo [4.3. 0] non-5-ene (DBN) has been shown to be an effective catalyst for the
regioselective Friedel− Crafts C-acylation of pyrroles and indoles in high yields. A detailed …

A dearomative oxidation of pyrroles to Δ3‐pyrrol‐2‐ones is described, which employs a
sulfoxide as oxidant, in conjunction with a carboxylic acid anhydride and a Brønsted acid …

Benzene-fused bis-(borondipyrromethene) s (bis-BODIPYs) were synthesized by retro-Diels–
Alder reaction of the corresponding bicyclo [2.2. 2] octadiene-fused (BCOD-fused) bis …

[4+ 1] Cycloaddition of α, β-unsaturated imidoyl cyanide (2-cyano-1-azadienes) with
isocyanides in the presence of a catalytic amount of AlCl3 afforded polysubstituted 2-amino …

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