Synthesis and reactivity of N-heterocyclic carbene (NHC)-supported heavier nitrile ylides

D Sarkar, S Dutta, F Hanusch, D Koley, S Inoue - Chemical Science, 2024 - pubs.rsc.org
The synthesis and isolation of stable heavier analogues of nitrile ylide as N-heterocyclic
carbene (NHC) adducts of phosphasilenyl-tetrylene [(NHC)(TerAr) Si (H) PE14 …

Organophosphorus Synthesis beyond P-Cl Bond: The Development of Shelf-stable Reagents for [RP] Transfer

VD Romanenko - Current Organic Chemistry, 2024 - benthamdirect.com
The direct chlorine-free incorporation of P1 units into organic molecules has very important
synthetical value owing to environmental considerations and the prospect of accessing …

Trapping an Elusive Phosphanyl‐Phosphaalumene

LS Szych, L Denker, J Feld… - Chemistry–A European …, 2024 - Wiley Online Library
We describe our efforts to access a compound with an Al= P double bond by reaction of Al
(Nacnac) towards [H2CN (Dipp)] 2P (PCO)(Nacnac= HC [C (Me) N (Dipp)] 2; Dipp= 2, 6 …

A Phosphanyl Phosphagermene and its Reactivity

J Feld, ES Yang, SJ Urwin… - Chemistry–A European …, 2024 - Wiley Online Library
Reaction of a nucleophilic germylene Ge [CH (SiMe3) 2] 2 with the phosphanyl
phosphaketene [{(H2C)(NDipp)} 2P] PCO induces decarbonylation to form a phosphanyl …