Recent advances in CO 2 capture and reduction

K Wei, H Guan, Q Luo, J He, S Sun - Nanoscale, 2022 - pubs.rsc.org
Given the continuous and excessive CO2 emission into the atmosphere from
anthropomorphic activities, there is now a growing demand for negative carbon emission …

Characterization of Intermediate Oxidation States in CO2 Activation

LG Dodson, MC Thompson… - Annual review of physical …, 2018 - annualreviews.org
Redox chemistry during the activation of carbon dioxide involves changing the charge state
in a CO2 molecular unit. However, such changes are usually not well described by integer …

An infrared study of CO 2 activation by holmium ions, Ho+ and HoO+

EI Brewer, AE Green, AS Gentleman… - Physical Chemistry …, 2022 - pubs.rsc.org
We report a combined experimental and computational study of carbon dioxide activation at
gas-phase Ho+ and HoO+ centres. Infrared action spectra of Ho (CO2) n+ and [HoO (CO2) …

Tuning the degree of CO 2 activation by carbon doping Cu n−(n= 3–10) clusters: an IR spectroscopic study

OV Lushchikova, M Szalay, T Höltzl, JM Bakker - Faraday Discussions, 2023 - pubs.rsc.org
Copper clusters on carbide surfaces have shown a high catalytic activity towards methanol
formation. To understand the interaction between CO2 and the catalytically active sites …

IR Signature of Size‐Selective CO2 Activation on Small Platinum Cluster Anions, Ptn (n=4–7)

AE Green, J Justen, W Schöllkopf… - Angewandte …, 2018 - Wiley Online Library
Infrared multiple photon dissociation spectroscopy (IR‐MPD) has been employed to
determine the nature of CO2 binding to size‐selected platinum cluster anions, Ptn−(n= 4–7) …

Gas-phase CO2 activation with single electrons, metal atoms, clusters, and molecules

R Wang, G Liu, SK Kim, KH Bowen, X Zhang - Journal of Energy Chemistry, 2021 - Elsevier
In this review, the history and outlook of gas-phase CO 2 activation using single electrons,
metal atoms, clusters (mainly metal hydride clusters), and molecules are discussed on both …

Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg .+ to CO2 in [MgCO2(H2O)n].+, n=0–8

E Barwa, TF Pascher, M Ončák… - Angewandte Chemie …, 2020 - Wiley Online Library
We investigate activation of carbon dioxide by singly charged hydrated magnesium cations
Mg.+(H2O) n, through infrared multiple photon dissociation (IRMPD) spectroscopy combined …

The metallo-formate anions, M (CO 2)−, M= Ni, Pd, Pt, formed by electron-induced CO 2 activation

G Liu, SM Ciborowski, Z Zhu, Y Chen… - Physical Chemistry …, 2019 - pubs.rsc.org
The metallo-formate anions, M (CO2)−, M= Ni, Pd, and Pt, were formed by electron-induced
CO2 activation. They were generated by laser vaporization and characterized by a …

Interaction of CO2 with Atomic Manganese in the Presence of an Excess Negative Charge Probed by Infrared Spectroscopy of [Mn(CO2)n] Clusters

MC Thompson, J Ramsay… - The Journal of Physical …, 2017 - ACS Publications
We report infrared photodissociation spectra of manganese–CO2 cluster anions,[Mn (CO2)
n]−(n= 2–10) to probe structural motifs characterizing the interaction between Mn and CO2 …

Carbon dioxide binding to metal oxides: Infrared spectroscopy of NbO2+ (CO2) n and TaO2+ (CO2) n complexes

A Iskra, AS Gentleman, EM Cunningham… - International Journal of …, 2019 - Elsevier
We report the results of an infrared photodissociation spectroscopy study to determine the
structures of gas–phase NbO 2 (CO 2) n+ and TaO 2 (CO 2) n+(n= 1–7) ion–molecule …