Supported catalysts based on layered double hydroxides for catalytic oxidation and hydrogenation: general functionality and promising application prospects
J Feng, Y He, Y Liu, Y Du, D Li - Chemical Society Reviews, 2015 - pubs.rsc.org
Oxidation and hydrogenation catalysis plays a crucial role in the current chemical industry
for the production of key chemicals and intermediates. Because of their easy separation and …
for the production of key chemicals and intermediates. Because of their easy separation and …
Surface chemistry of Au/TiO2: Thermally and photolytically activated reactions
DA Panayotov, JR Morris - Surface Science Reports, 2016 - Elsevier
The fascinating particle size dependence to the physical, photophysical, and chemical
properties of gold has motivated thousands of studies focused on exploring the ability of …
properties of gold has motivated thousands of studies focused on exploring the ability of …
The mechanism of ethylene epoxidation catalysis
MO Özbek, RA Van Santen - Catalysis letters, 2013 - Springer
Today ethylene oxide can be produced industrially with~ 90% selectivity through the
epoxidation of ethylene over silver catalyst. The past decades there has been a substantial …
epoxidation of ethylene over silver catalyst. The past decades there has been a substantial …
Silver residues as a possible key to a remarkable oxidative catalytic activity of nanoporous gold
LV Moskaleva, S Röhe, A Wittstock… - Physical Chemistry …, 2011 - pubs.rsc.org
Recently, several forms of unsupportedgold were shown to display a remarkable activity to
catalyze oxidation reactions. Experimental evidence points to the crucial role of residual …
catalyze oxidation reactions. Experimental evidence points to the crucial role of residual …
Why silver is the unique catalyst for ethylene epoxidation
The activities of Cu2O (001), Ag2O (001), and Au2O (001) surfaces for direct ethylene
epoxidation and alternative paths for EO isomerization are studied. Among these three oxide …
epoxidation and alternative paths for EO isomerization are studied. Among these three oxide …
Going Beyond Silver in Ethylene Epoxidation with First‐Principles Catalyst Screening
Ethylene epoxidation is industrially and commercially one of the most important selective
oxidations. Silver catalysts have been state‐of‐the‐art for decades, their efficiency steadily …
oxidations. Silver catalysts have been state‐of‐the‐art for decades, their efficiency steadily …
Icosahedral Crown Gold Nanocluster Au43Cu12 with High Catalytic Activity
Structural and catalytic properties of the gold alloy nanocluster Au43Cu12 are investigated
using a density-functional method. In contrast to the pure Au55 nanocluster, which exhibits a …
using a density-functional method. In contrast to the pure Au55 nanocluster, which exhibits a …
Unraveling molecular transformations on surfaces: a critical comparison of oxidation reactions on coinage metals
The coinage metals, copper, silver, and gold, have unique characteristics for selective
oxidation catalysis, particularly for partial oxidation of alcohols and olefins. A basic …
oxidation catalysis, particularly for partial oxidation of alcohols and olefins. A basic …
Role of Au− C interactions on the catalytic activity of AU nanoparticles supported on TiC (001) toward molecular oxygen dissociation
JA Rodriguez, L Feria, T Jirsak… - Journal of the …, 2010 - ACS Publications
High-resolution photoemission and density functional calculations on realistic slab surface
models were used to study the interaction and subsequent dissociation of O2 with Au …
models were used to study the interaction and subsequent dissociation of O2 with Au …
Active site of catalytic ethene epoxidation: machine-learning global pathway sampling rules out the metal sites
Ethene epoxidation on Ag-based catalysts, an important heterogeneous catalytic reaction
with large-scale global wide production, has generated continuous debate on the active site …
with large-scale global wide production, has generated continuous debate on the active site …