C–H activation: toward sustainability and applications

T Dalton, T Faber, F Glorius - ACS Central Science, 2021 - ACS Publications
Since the definition of the “12 Principles of Green Chemistry” more than 20 years ago,
chemists have become increasingly mindful of the need to conserve natural resources and …

Recent advances in enantioselective Pd-catalyzed allylic substitution: from design to applications

O Pamies, J Margalef, S Canellas, J James… - Chemical …, 2021 - ACS Publications
This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Strategies for Nucleophilic C(sp3)–(Radio)Fluorination

INM Leibler, SS Gandhi, MA Tekle-Smith… - Journal of the …, 2023 - ACS Publications
This Perspective surveys the progress and current limitations of nucleophilic fluorination
methodologies. Despite the long and rich history of C (sp3)–F bond construction in chemical …

Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

The fluorination of C− H bonds: developments and perspectives

R Szpera, DFJ Moseley, LB Smith… - Angewandte Chemie …, 2019 - Wiley Online Library
This Review summarizes advances in fluorination by C (sp2)− H and C (sp3)− H activation.
Transition‐metal‐catalyzed approaches championed by palladium have allowed the …

Ligand-promoted palladium-catalyzed aerobic oxidation reactions

D Wang, AB Weinstein, PB White, SS Stahl - Chemical reviews, 2017 - ACS Publications
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Ionic liquids in selective oxidation: catalysts and solvents

C Dai, J Zhang, C Huang, Z Lei - Chemical reviews, 2017 - ACS Publications
Selective oxidation has an important role in environmental and green chemistry (eg,
oxidative desulfurization of fuels and oxidative removal of mercury) as well as chemicals and …

The Cross‐Dehydrogenative Coupling of C H Bonds: A Versatile Strategy for C C Bond Formations

SA Girard, T Knauber, CJ Li - … Chemie International Edition, 2014 - Wiley Online Library
Over the last decade, substantial research has led to the introduction of an impressive
number of efficient procedures which allow the selective construction of C C bonds by …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …