Dinuclear lanthanide–lithium complexes based on fluorinated β-diketonate with acetal group: Magnetism and effect of crystal packing on mechanoluminescence

DN Bazhin, YS Kudyakova, AS Bogomyakov… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The synthesis of novel dinuclear lanthanide complexes with formulas [(LnL3)(LiL)(MeOH)](1–
3) and [(LnL3)(LiL)(H2O)](4–6)(Ln= Eu (III), Tb (III), Dy (III)) based on functionalized lithium β …

The Impact of the Alkali Metal Ion on the Crystal Structure and (Mechano) luminescence of Terbium (III) Tetrakis (β‐diketonates)

YS Kudyakova, PA Slepukhin… - European Journal of …, 2020 - Wiley Online Library
The novel terbium (III) tetrakis (β‐diketonates) M [TbL4] with different alkali metal
counterions (Na, K, Cs) based on functionalized trifluoromethylated β‐diketonate are …

Multi-Functional Single-Source Molecular Precursors for Carbon-Coated Mixed-Metal Phosphates

H Han, Y Zhang, Z Zhou, JC Carozza, Z Wei… - Inorganic …, 2023 - ACS Publications
We introduce a new synthetic concept that can be broadly adopted for the low-temperature
preparation of mixed-metal energy storage materials, such as phosphates, silicates …

Bimetallic nickel–cobalt hydrides in H 2 activation and catalytic proton reduction

X Chu, J Jin, B Ming, M Pang, X Yu, CH Tung… - Chemical …, 2019 - pubs.rsc.org
The synergism of the electronic properties of nickel and cobalt enables bimetallic NiCo
complexes to process H2. The nickel–cobalt hydride [(dppe) Ni (pdt)(H) CoCp*]+([1H]+) …

Generation of local redox potential from confined nano-bimetals in porous metal silicate materials for high-performance catalysis

YY Liu, XK Shi, CD Wu - Catalysis Science & Technology, 2022 - pubs.rsc.org
Partial hydrogenation of polycyclic aromatic hydrocarbons (PAHs) could not only produce
highly value-added chemicals but also reduce environmental pollution; however, the partial …

Trickier than It Looks: Isomerization between Five- and Six-Coordinated Zinc in Heterometallic Li2Zn2 Molecule

Y Zhang, H Han, Z Wei, EV Dikarev - Inorganic Chemistry, 2024 - ACS Publications
This report describes the synthesis and characterization of two hetero bi metallic Li–Zn
coordination isomers [Li2Zn2 (tbaoac) 6](tbaoac= tert-butyl acetoacetato) that have been …

Heterotrimetallic Precursor with 2:2:1 Metal Ratio Requiring at Least a Pentanuclear Molecular Assembly

H Han, JC Carozza, Z Zhou, Y Zhang… - Journal of the …, 2020 - ACS Publications
This work represents an important step in the quest to make hetero multi metallic molecules
featuring specific metal types and complicated metal ratios. The rational design, synthesis …

Volatile Li-Ni heteroleptic complexes: Effect of the ligand composition on structure and thermal properties

VV Krisyuk, AS Sukhikh, NA Kryuchkova… - Polyhedron, 2024 - Elsevier
A series of volatile Li-Ni heteroleptic complexes [Ni (SB) Li (dkt)] were prepared as single-
source precursors (SSP) for thin-film lithium ion microbatteries, Ni (SB)= Ni (acacen)(1) or Ni …

Crystallization Features of LiI-CrIII Coordination Compounds with Cyclobutane-1,1-Dicarboxylic Acid Anions

ES Bazhina, MA Shmelev, MA Kiskin… - Journal of Structural …, 2023 - Springer
For the goal of preparing LiI–CrIII heterometallic coordination compounds, we studied the
reaction of Cr (NO3) 3· 9H2O and Li2 (cbdc)(obtained by the neutralization of LiOH· H2O …

Three to tango requires a site-specific substitution: hetero tri metallic molecular precursors for high-voltage rechargeable batteries

H Han, Z Wei, AS Filatov, JC Carozza, M Alkan… - Chemical …, 2019 - pubs.rsc.org
Design of heterotrimetallic molecules, especially those containing at least two different
metals with close atomic numbers, radii, and the same coordination number/environment is …