Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …

Metal porphyrins (MP) and metal phthalocyanines (MPc) have precisely tailored structural
and electronic properties, and their coordination environment and electronic structure can …

Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …

Iron porphyrins with one or four tertiary amine groups in their second sphere are used to
investigate the electrochemical O2 reduction reaction (ORR) in organic (homogeneous) and …

A newly designed copper complex of 5, 15-bis (pentafluorophenyl)-10, 20-bis (o-carborane)
porphyrin (1) was synthesized and tested for the electrocatalytic hydrogen evolution reaction …

The extraordinary potential of hydrogen as a clean and sustainable fuel has sparked the
interest of the scientific community to find environmentally friendly methods for its production …

The active sites of metalloenzymes involved in small molecules activation often contain
pendant bases that act as proton relay promoting proton‐coupled electron‐transfer …

Elucidating the effects of various structural components on energy‐related small molecule
activation is of fundamental and practical significance. Herein the inhibition effect of …

For a future hydrogen economy, non‐precious metal catalysts for the water splitting
reactions are needed that can be implemented on a global scale. Metal‐nitrogen‐carbon …

A μ-oxo diiron complex, featuring the pyridine-2, 6-dicarboxamide-based thiazoline-derived
redox-active ligand, H2L (H2L= N2, N6-bis (4, 5-dihydrothiazol-2-yl) pyridine-2, 6 …