Ion dissociation in ionic liquids and ionic liquid solutions

O Nordness, JF Brennecke - Chemical reviews, 2020 - ACS Publications
The extent to which cations and anions in ionic liquids (ILs) and ionic liquid solutions are
dissociated is of both fundamental scientific interest and practical importance because ion …

Microstructural and dynamical heterogeneities in ionic liquids

YL Wang, B Li, S Sarman, F Mocci, ZY Lu… - Chemical …, 2020 - ACS Publications
Ionic liquids (ILs) are a special category of molten salts solely composed of ions with varied
molecular symmetry and charge delocalization. The versatility in combining varied cation …

Perspectives for polymer electrolytes: a view from fundamentals of ionic conductivity

V Bocharova, AP Sokolov - Macromolecules, 2020 - ACS Publications
We present a brief overview of current developments in the field of polymer electrolytes, with
the focus on single-ion conducting polymers. The latter have significant advantages relative …

Ion transport in (localized) high concentration electrolytes for Li-based batteries

HK Bergstrom, BD McCloskey - ACS Energy Letters, 2024 - ACS Publications
High concentration electrolytes (HCEs) and localized high concentration electrolytes
(LHCEs) have emerged as promising candidates to enable higher energy density Li-ion …

Ionic liquids at electrified interfaces

MV Fedorov, AA Kornyshev - Chemical reviews, 2014 - ACS Publications
Until recently,“room-temperature”(< 100− 150 C) liquidstate electrochemistry was mostly
electrochemistry of diluted electrolytes 1− 4 where dissolved salt ions were surrounded by a …

Targeted modifications in ionic liquids–from understanding to design

F Philippi, T Welton - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Ionic liquids are extremely versatile and continue to find new applications in academia as
well as industry. This versatility is rooted in the manifold of possible ion types, ion …

Cation‐assisted lithium‐ion transport for high‐performance peo‐based ternary solid polymer electrolytes

J Atik, D Diddens, JH Thienenkamp… - Angewandte Chemie …, 2021 - Wiley Online Library
N‐alkyl‐N‐alkyl pyrrolidinium‐based ionic liquids (ILs) are promising candidates as non‐
flammable plasticizers for lowering the operation temperature of poly (ethylene oxide)(PEO) …

Mixtures of ionic liquids

H Niedermeyer, JP Hallett, IJ Villar-Garcia… - Chemical Society …, 2012 - pubs.rsc.org
Simple ionic liquids have long been held to be designer solvents, based upon the ability to
independently vary their cations and anions. The formation of mixtures of ionic liquids …

Sulfolane-based highly concentrated electrolytes of lithium Bis (trifluoromethanesulfonyl) amide: ionic transport, Li-Ion coordination, and Li–S battery performance

A Nakanishi, K Ueno, D Watanabe… - The Journal of …, 2019 - ACS Publications
Following our recent study demonstrating predominant Li-ion hopping conduction in
sulfolane (SL)-based highly concentrated electrolytes with LiBF4, LiClO4, and lithium bis …

Glyme–lithium salt equimolar molten mixtures: concentrated solutions or solvate ionic liquids?

K Ueno, K Yoshida, M Tsuchiya… - The Journal of …, 2012 - ACS Publications
To demonstrate a new family of ionic liquids (ILs), ie,“solvate” ionic liquids, the properties
(thermal, transport, and electrochemical properties, Lewis basicity, and ionicity) of equimolar …