Selective gas adsorption and separation in metal–organic frameworks

JR Li, RJ Kuppler, HC Zhou - Chemical Society Reviews, 2009 - pubs.rsc.org
Adsorptive separation is very important in industry. Generally, the process uses porous solid
materials such as zeolites, activated carbons, or silica gels as adsorbents. With an ever …

Development of computational methodologies for metal–organic frameworks and their application in gas separations

Q Yang, D Liu, C Zhong, JR Li - Chemical Reviews, 2013 - ACS Publications
Under the impetus of some breakthrough studies, 1− 6 associated research on metal−
organic frameworks (MOFs) has rapidly developed into one of the highly unique areas in …

Metal-organic frameworks for C6–C8 hydrocarbon separations

Z Zhang, SB Peh, C Kang, K Chai, D Zhao - EnergyChem, 2021 - Elsevier
Hydrocarbon separations are crucial to the chemical industry for the production of valuable
feedstocks. However, their structural and chemical similarities have proven daunting …

Hydrogen isotope separation in confined nanospaces: carbons, zeolites, metal–organic frameworks, and covalent organic frameworks

JY Kim, H Oh, HR Moon - Advanced Materials, 2019 - Wiley Online Library
One of the greatest challenges of modern separation technology is separating isotope
mixtures in high purity. The separation of hydrogen isotopes can create immense economic …

Hydrogen adsorption and storage on porous materials

KM Thomas - Catalysis today, 2007 - Elsevier
The development of safe and efficient methods of hydrogen storage is a prerequisite for the
use of hydrogen with fuel cells for transport applications. In this paper, results available for …

Surface Interactions and Quantum Kinetic Molecular Sieving for H2 and D2 Adsorption on a Mixed Metal−Organic Framework Material

B Chen, X Zhao, A Putkham, K Hong… - Journal of the …, 2008 - ACS Publications
A rational strategy has been used to immobilize open metal sites in ultramicroporosity for
stronger binding of multiple H2 molecules per unsaturated metal site for H2 storage …

A mini-review of the current progress and future challenges of zeolites for hydrogen isotopes separation through a quantum effect

SH So, H Oh - International Journal of Hydrogen Energy, 2024 - Elsevier
Deuterium or tritium, which are rare isotopologues of hydrogen, are in high demand across
various industries; thus it is crucial to develop a separation technology for hydrogen …

Exploiting diffusion barrier and chemical affinity of metal–organic frameworks for efficient hydrogen isotope separation

JY Kim, R Balderas-Xicohténcatl, L Zhang… - Journal of the …, 2017 - ACS Publications
Deuterium plays a pivotal role in industrial and scientific research, and is irreplaceable for
various applications such as isotope tracing, neutron moderation, and neutron scattering. In …

Adsorption and desorption of hydrogen on metal–organic framework materials for storage applications: comparison with other nanoporous materials

KM Thomas - Dalton transactions, 2009 - pubs.rsc.org
Hydrogen adsorption on porous materials is one of the possible methods proposed for
hydrogen storage for transport applications. High pressure experimental studies of a wide …

Non-classical hydrogen storage mechanisms other than chemisorption and physisorption

S Liu, J Liu, X Liu, JX Shang, R Yu, J Shui - Applied Physics Reviews, 2022 - pubs.aip.org
The hydrogen storage mechanism of materials is usually divided into chemisorption and
physisorption according to the way the material interacts with hydrogen. Chemisorption …