Hydroamination: direct addition of amines to alkenes and alkynes

TE Muller, KC Hultzsch, M Yus, F Foubelo… - Chemical …, 2008 - ACS Publications
Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

The chemistry of vicinal diamines

D Lucet, T Le Gall, C Mioskowski - … Chemie International Edition, 1998 - Wiley Online Library
Especially in the field of enantioselective synthesis, vicinal diamines (1, 2‐diamines) 1 and
compounds easily prepared from them—such as 1, 2‐bisimines, 1, 2‐diamides, or …

Oxidative diamination of alkenes with ureas as nitrogen sources: Mechanistic pathways in the presence of a high oxidation state palladium catalyst

K Muñiz, CH Hövelmann, J Streuff - Journal of the American …, 2008 - ACS Publications
A first palladium-catalyzed intramolecular diamination of unfunctionalized terminal alkenes
has recently been reported. This study investigates the details of its mechanistic course …

Fischer Carbene Complexes as Chemical Multitalents: The Incredible Range of Products from Carbenepentacarbonylmetal α,β‐Unsaturated Complexes

A de Meijere, H Schirmer… - Angewandte Chemie …, 2000 - Wiley Online Library
The metal carbene complexes, discovered by EO Fischer at the start of the 1960s and
carrying his name, have since proved themselves to be irreplaceable building blocks for …

Photoinduced olefin diamination with alkylamines

S Govaerts, L Angelini, C Hampton… - Angewandte Chemie …, 2020 - Wiley Online Library
Vicinal diamines are ubiquitous materials in organic and medicinal chemistry. The direct
coupling of olefins and amines would be an ideal approach to construct these motifs …

Methods for direct alkene diamination, new & old

S De Jong, DG Nosal, DJ Wardrop - Tetrahedron, 2012 - Elsevier
The 1, 2-diamine moiety is an ubiquitous structural motif found in a wealth of natural
products, including non-proteinogenic amino acids and alkaloids, in pharmaceutical agents …

Regioselective hydroamination of unactivated olefins with diazirines as a diversifiable nitrogen source

Q Xing, PP Chandrachud, K Tillett… - Nature …, 2024 - nature.com
Nitrogen-containing compounds, such as amines, hydrazines, and heterocycles, play an
indispensable role in medicine, agriculture, and materials. Alkylated derivatives of these …

Transition‐Metal‐Catalyzed Diamination of Olefins

RM de Figueiredo - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Diaminations are a girl's best friend: New reactions in the field of transition‐metal‐catalyzed
diamination of olefins provide a powerful tool for the elaboration of more complex molecules …

Oxidative interception of the hydroamination pathway: a gold‐catalyzed diamination of alkenes

A Iglesias, K Muniz - Chemistry–A European Journal, 2009 - Wiley Online Library
A complimentary diamination of alkenes by using homogeneous gold catalysts is described.
The reaction is one of very few examples of homogeneous gold oxidation catalysis and …

Die chemie vicinaler diamine

D Lucet, T Le Gall, C Mioskowski - Angewandte Chemie, 1998 - Wiley Online Library
Vor allem bei enantioselektiven Synthesen werden vicinale Diamine (1, 2‐Diamine) 1 und
Verbindungen, die auf einfachem Weg aus diesen erhalten werden können–wie 1, 2 …