Exploring the Interrelation between Urbach Energy and Dielectric Constant in Hf-Substituted BaTiO3

OV Rambadey, A Kumar, A Sati, PR Sagdeo - ACS omega, 2021 - ACS Publications
The variation of dielectric constant (εr) in the low-frequency region (∼ 106 Hz) in Hf-
substituted BaTiO3 has been modelled considering the electronic disorder in the form of …

Temperature-Dependent Delocalization of Oxygen Vacancies in La-Substituted CeO2

M Gupta, SC Shirbhate, OV Rambadey… - ACS Applied Energy …, 2022 - ACS Publications
Signature of oxygen ion conductivity in hydrothermally synthesized Ce1–x La x O2− δ (0≤
x≤ 0.50) solid-electrolyte samples has been investigated. Room-temperature Raman …

Investigating the correlation between the Urbach energy and asymmetry parameter of the Raman mode in semiconductors

OV Rambadey, A Kumar, PR Sagdeo - Physical Review B, 2021 - APS
A quantitative correlation between the Urbach energy (E u) and asymmetry parameter q of
Raman spectra has been derived. For this purpose, the effect of electronic disorder (∼ E u) …

Role of Laser Excitation Wavelength and Power in the Fano Resonance Scattering in RFe0.50Cr0.50O3 (R = Sm, Er, and Eu): A Brief Raman Study

A Kumar, OV Rambadey, H Rai… - The Journal of Physical …, 2022 - ACS Publications
Here in the present report, we have extensively studied the impact of the excitation laser
wavelength and laser power on the Raman spectrum of mixed Fe-Cr-based rare-earth …

Unorthodox Approach to Realize the Correlation between the Dielectric Constant and Electronic Disorder in Cr-Doped PrFeO3

A Kumar, OV Rambadey… - The Journal of Physical …, 2021 - ACS Publications
Here, in the present report, an attempt has been made to explore a quantitative correlation
between the Urbach energy (EU) and the dielectric constant (ε) by using a Bohr-like model …

Analysis of structural disorder on Raman spectra of semiconductors

OV Rambadey, M Gupta, A Kumar… - Journal of Applied …, 2023 - pubs.aip.org
This Tutorial provides a fundamental discussion on the lattice dynamics of physical systems
introduced with disorder and, hence, the importance of Raman spectroscopy (RS) technique …

Origin of natural and magnetic field induced polar order in orthorhombic

A Kumar, MK Warshi, A Sagdeo, M Krzystyniak… - Physical Review B, 2021 - APS
Here, we report the possible origin of natural and magnetic field induced polar order near
room temperature (RT) in Pr Fe 1/2 Cr 1/2 O 3. The temperature-dependent Raman …

Methodology to Probe Disorder Contribution in Raman Linewidth via Optical Absorption Spectroscopy in Orthoferrite EuFeO3

OV Rambadey, A Kumar, K Kumar… - The Journal of …, 2022 - ACS Publications
The individual impact of disorder on different phonon modes has been investigated for
orthoferrite EuFeO3 by perceiving a correlation between temperature-dependent Raman …

Probing the effect of R-cation radii on structural, vibrational, optical, and dielectric properties of rare earth (R= La, Pr, Nd) aluminates

M Gupta, OV Rambadey, PR Sagdeo - Ceramics International, 2022 - Elsevier
The present study correlates the effect of R-cation radii on structural, vibrational, optical, and
dielectric properties of rhombohedral rare earth aluminates RAlO 3 (R= La, Pr, Nd). The …

Phonon-mode-specific lattice dynamical coupling of carriers in semiconductors using Raman and optical spectroscopic techniques

OV Rambadey, M Gupta, PR Sagdeo - Physical Review B, 2022 - APS
We demonstrate a methodology for quantitative estimation of electron-phonon coupling
(EPC) for each phonon mode taking base from second-order correction in polaron-energy …