Recent advances in the preparation and application of allylboron species in organic synthesis

C Diner, KJ Szabo - Journal of the American Chemical Society, 2017 - ACS Publications
Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

Control of selectivity in palladium (II)-catalyzed oxidative transformations of allenes

B Yang, Y Qiu, JE Bäckvall - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Oxidation reactions play a central role in organic synthesis, and it is highly
desirable that these reactions are mild and occur under catalytic conditions. In Nature …

Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2

J Zhang, W Dai, Q Liu, S Cao - Organic letters, 2017 - ACS Publications
A novel and efficient method for the synthesis of (Z)-fluorinated alkenylboronic acid pinacol
esters via Cu-catalyzed stereoselective borylation of gem-difluoroalkenes using bis …

Iron‐Catalyzed Cross‐Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols

D Posevins, A Bermejo‐López… - Angewandte Chemie …, 2021 - Wiley Online Library
Herein we disclose an iron‐catalyzed cross‐coupling reaction of propargyl ethers with
Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a …

Oxidative coupling mechanisms: current state of understanding

I Funes-Ardoiz, F Maseras - Acs Catalysis, 2018 - ACS Publications
Oxidative coupling reactions, where two electrons are released from the reactants and
trapped by an oxidant, have arisen as a versatile alternative to cross-coupling in chemical …

Formal nucleophilic borylation and borylative cyclization of organic halides

K Kubota, H Iwamoto, H Ito - Organic & Biomolecular Chemistry, 2017 - pubs.rsc.org
This review describes recent advances in direct borylation reactions of organic halides,
including both transition-metal-catalyzed and metal-free methods. Since the pioneering work …

Palladium-Catalyzed Synthesis of Dibenzosilepin Derivatives via 1,n-Palladium Migration Coupled with anti-Carbopalladation of Alkyne

T Tsuda, SM Choi, R Shintani - Journal of the American Chemical …, 2021 - ACS Publications
Catalytic reactions involving 1, n-metal migration represent a powerful method for the
synthesis of complex molecules from simple precursors through the activation of C–H bonds …

Palladium-catalyzed trans-selective synthesis of spirocyclic cyclobutanes using α, α-dialkylcrotyl-and allylhydrazones

IK Eckart-Frank, SM Wilkerson-Hill - Journal of the American …, 2023 - ACS Publications
Herein, we demonstrate the use of E/Z mixtures of α, α-disubstituted crotylhydrazones to
obtain spirocyclic vinylcyclobutanes in a diastereoselective fashion. We show 24 examples …

Palladium-catalyzed enantioselective carbonylation reactions

JB Peng, XL Liu, L Li, XF Wu - Science China Chemistry, 2022 - Springer
Carbonylation, one of the most powerful approaches to the preparation of carbonylated
compounds, has received significant attention from researchers active in various fields …

Palladium-Catalyzed Dehydrogenative Carbonylative Esterification of Allenoic Acids for the Synthesis of γ-Butyrolactone Derivatives

B Wang, M Ren, N Iqbal, X Mu, JE Backvall… - Organic …, 2024 - ACS Publications
A highly efficient dehydrogenative carbonylative esterification of allenoic acids using Pd-
catalysis was developed, providing a novel approach to synthesizing esterified γ …