Proximity Effects in Organic Chemistry—The Photoelectron Spectroscopic Investigation of Non‐Bonding and Transannular Interactions

HD Martin, B Mayer - Angewandte Chemie International Edition …, 1983 - Wiley Online Library
Classical structural formulas often convey the impression only those relationships between
the atoms are of importance which hold a molecule together as symbolized by the chemical …

A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s:  Band Gap Tuning via Conformational Control

BL Lucht, SSH Mao, TD Tilley - Journal of the American Chemical …, 1998 - ACS Publications
A series of substituted poly (p-phenylenediyne) s (1a− f) was synthesized by the palladium-
catalyzed cross-coupling condensation of terminal dialkynylalkanes with substituted …

Photoelectron spectra and bonding in small ring hydrocarbons

R Gleiter - Spectroscopy, 1979 - Springer
Photoelectron spectra and bonding in small ring hydrocarbons Page 1 Photoelectron Spectra
and Bonding in Small Ring Hydrocarbons Rolf Gleiter Institut f'tir Organische Chemie der …

Conformational Analysis by Photoelectron Spectroscopy

M Klessinger, P Rademacher - … Chemie International Edition in …, 1979 - Wiley Online Library
The conformation of organic molecules may be determined by means of photoelectron (PE)
spectroscopy if there are orbital interactions present which depend on a dihedral angle …

Der Einfluß des Dien‐1, 4‐Abstandes auf die Reaktivität bei Diels‐Alder‐Reaktionen

R Sustmann, M Böhm, J Sauer - Chemische Berichte, 1979 - Wiley Online Library
Die Reaktivität von Cyclopentadien und cis‐fixierten Di‐exo‐methylenverbindungen in Diels‐
Alder‐Reaktionen wird im Rahmen des Grenzorbitalmodells untersucht. Es wird gezeigt …

Elektronenstruktur von Alkyl‐aryl‐und Alkyl‐vinyl‐ethern

HF Und, M Klessinger - Chemische Berichte, 1979 - Wiley Online Library
Um das Ausmaß der Konjugation zwischen π‐Elektronen der CC‐Doppelbindung und
freien Elektronenpaaren am O‐Atom α, β‐ungesättigter Ether zu ermitteln, wurden die …

Konformationsanalyse durch Photoelektronen‐Spektroskopie

M Klessinger, P Rademacher - Angewandte Chemie, 1979 - Wiley Online Library
Abstract Die Konformation organischer Moleküle läßt sich durch Photoelektronen‐(PE‐)
Spektroskopie bestimmen, wenn vom Diederwinkel abhängige Orbitalwechselwirkungen …

Substituent effects in [2. sigma.+ 2. sigma.+ 2. sigma.] thermal decarbonylation of cage ketones. Remarkably effective elongation of strained carbon-carbon bond by …

K Harano, T Ban, M Yasuda, E Osawa… - Journal of the …, 1981 - ACS Publications
Strained pentacyclicketones (5a-d) were prepared in high yields by photoinduced [4+ 2]
cycloadduct of 7V-(ethoxycarbonyl) azepine with substitutedcyclopentadienones. The …

The structure and energies of some unsaturated four‐membered ring carbocycles

NL Allinger, Y Yuh, JT Sprague - Journal of Computational …, 1980 - Wiley Online Library
A number of cyclobutane derivatives containing one or more double bonds in endo‐or
exocyclic positions have been studied by the molecular mechanics method within the …

Synthesis and characterization of the negative ion of non-Kekulé benzene

BT Hill, RR Squires - Journal of the Chemical Society, Perkin …, 1998 - pubs.rsc.org
The 2, 4-dimethylenecyclobutane-1, 3-diyl negative ion 2 has been generated in the gas
phase from the reaction of atomic oxygen anion with 1, 3-dimethylenecyclobutane 3. This …