High‐valent cyclopentadienyl cobalt catalysis is a versatile tool for sustainable C− H bond
functionalizations. To harness the full potential of this strategy, control of the stereoselectivity …

C− N bond formation reactions have garnered a lot of interest in recent years due to the
predominance of nitrogen‐containing compounds in most pharmacological medications …

A variety of biologically active molecules, pharmaceuticals, and natural products consist of a
nitrogen-containing heterocyclic backbone. The majority of them are isoquinolones, indoles …

A novel ruthenium-catalyzed [5+ 1] annulation of 2-alkenylanilines with sulfoxonium ylides
was developed for the rapid assembly of highly functionalized quinolines. This new catalytic …

Co (III)-catalyzed highly regio-and stereoselective direct C6 olefination of 2-pyridones with
alkynes has been developed with the assistance of chelation. Upon variation of the reaction …

During the last two decades, impressive advancements have been achieved in transition
metal‐catalyzed chelation‐assisted C—H functionalization reaction. While reactions in this …

We have developed Cp* Co (III)-catalyzed redox-neutral synthesis of 3, 4-unsubstituted
isoquinoline 1 (2 H)-ones at ambient temperature using N-chloroamides as a starting …

Herein, we report the development of a tailored cobalt catalyst system of Cp* Co (III)(LX)
toward intramolecular C–H nitrene insertion of azidoformates to afford cyclic carbamates …

An efficient protocol for the synthesis of biologically essential pyrroloquinolinones has been
developed under Cp* CoIII catalysis, which involves a cascade reaction of C (7)–H …

A general and efficient Cp* CoIII-catalyzed C2-thiolation and C2, C3-dithiolation of indole
derivatives has been achieved employing N-(aryl/alkylthio) succinimide as a thiolating …