Isocyanides are well known for their multi-component reactions (MCR), such as the
Passerini reaction and the Ugi reaction, with diverse molecular skeletons, high functional …

Diacyl peroxides,(RCO2) 2, are readily available and widely used reagents for organic
synthesis, because they can serve as electrophiles, oxidants, and radical sources. Recently …

We report the challenging direct carbamoylation or cyanation of benzylic C (sp3)–H bonds
with an isocyanide via an electrochemical process giving rise to structures that are …

A series of N-aroyloxyquinuclidinium salts were prepared and used as reagents to perform
efficient three-component Ritter–Mumm-type oxidative C–H imidation of donors of 1° and 2° …

The possibility of harnessing the photoactivity of isocyanides in the development of metal-
free Ugi-like visible light photo-triggered multicomponent transformations has been reported …

Hydroxyl radicals (˙ OH) as one of the highly reactive species can react unselectively with a
wide range of chemicals. The˙ OH radicals are typically generated under harsh conditions …

The consecutive addition of acyl radicals and N-alkylindole nucleophiles to styrenes was
established, as well as some additional radical–nucleophile combinations. Both aryl and …

A transition‐metal‐free direct electrolytic C− H amination involving an electrochemically
generated nitrenium ion intermediate has been developed. The electrosynthesis takes place …

An efficient, metal‐free oxidation method of the N‐ortho C (sp3)− H bond of amide via visible‐
light irradiation has been developed. A broad range of imides can be facilely obtained at …

We report the multigram scale synthesis of heterodimeric β-truxinic imides piperarborenines
CE using a catechol-tethered diastereoselective intramolecular [2+ 2] photocycloaddition …