Co(II)-Catalyzed Additive-Free Transfer Hydrogenation of N-Heteroarenes at Room Temperature

D Mahapatra, A Sau, T Ghosh, A Roy, S Kundu - Organic Letters, 2024 - ACS Publications
Traditional catalyst development relies on multistep synthesis and isolation of ligand and
precatalyst. Designing a catalytic system that can be assembled in situ from easily …

Ir-catalyzed selective reductive N-formylation and transfer hydrogenation of N-heteroarenes

R Luo, S Wang, Y Liang, J Tong, J Liao… - Organometallics, 2024 - ACS Publications
Selective functionalization has numerous potential applications in the modification of
bioactive compounds and pharmaceuticals. Herein, we advance a new approach for the …

Cyclopentadienone Iridium Bipyridyl Complexes: Acid-Stable Transfer Hydrogenation Catalysts

DP Marron, CM Galvin, RM Waymouth - Organometallics, 2023 - ACS Publications
The synthesis, structure, and reactivity of a series of cyclopentadienone and
hydroxycyclopentadienyl 4, 4′-dimethyl-2, 2′-bipyridine (dmbpy) iridium complexes …

Methyl Formate, an Alternative Transfer Hydrogenating Agent for Chemoselective Reduction of N-Heteroarenes and Azoarenes

A Sau, D Mahapatra, A Maji, S Dey, A Roy… - Organic …, 2024 - ACS Publications
The search for efficient molecular hydrogen precursors and their catalytic exploration is
necessary for the evolution of catalytic transfer hydrogenation. Methyl formate (MF) having …