Emulsion polymerization: Kinetic and mechanistic aspects

M Nomura, H Tobita, K Suzuki - Polymer Particles: -/-, 2005 - Springer
The current understanding of the kinetics and mechanisms of batch and continuous
emulsion polymerizations is summarized from the viewpoints of particle formation and …

Controversies on the mechanism and kinetics of emulsion polymerization: An updated critical review

J Herrera-Ordonez - Advances in Colloid and Interface Science, 2023 - Elsevier
Conventional emulsion polymerization (EP) is a process via free radicals whose driving
force for its development has been its versatility to generate polymer colloids with ad hoc …

Is modeling the PSD in emulsion polymerization a finished problem? An overview

N Sheibat‐Othman, HM Vale, JM Pohn… - Macromolecular …, 2017 - Wiley Online Library
Significant progress has been made over the past 20–30 years in terms of the ability to
develop and solve mechanistic models of emulsion polymerization processes, and in …

On the evolution of the rate of polymerization, number and size distribution of particles in styrene emulsion polymerization above CMC

S Carro, J Herrera‐Ordonez… - Journal of Polymer …, 2010 - Wiley Online Library
This work is an extension of a communication reported by two of the authors [Carro and
Herrera‐Ordoñez, Macromol Rapid Commun 2006, 27, 274], where bimodal particle size …

[图书][B] Encyclopedia of surface and colloid science, 2004 update supplement

P Somasundaran - 2014 - taylorfrancis.com
Appending the Encyclopedia of Surface and Colloid Science by 42 entries as well as 3800
new citations, 1012 equations, and 485 illustrations and chemical structures, this important …

Phase separation kinetics of polyelectrolyte solutions

S Kanai, M Muthukumar - The Journal of chemical physics, 2007 - pubs.aip.org
The kinetics of phase separation of aqueous solutions of sodium-poly (styrene
sulfonate)(NaPSS) containing barium chloride (Ba Cl 2) is studied by static and dynamic …

Synthesis of monodisperse, large scale and high solid content latexes of poly(n-butyl acrylate) by a one-step batch emulsion polymerization

B Liu, M Zhang, C Zhou, L Ren, H Cheng, Y Ao… - Colloid and Polymer …, 2013 - Springer
Seeded emulsion polymerization and agglomerating method were well-known techniques
for the production of polymeric latexes with large particle size and high solid content …

The kinetics of emulsion polymerization: some controversial aspects

J Herrera‐Ordonez, R Olayo, S Carro - Journal of Macromolecular …, 2004 - Taylor & Francis
Advances in the study of emulsion polymerization (EP) have allowed the clarification of
some aspects of the mechanism and kinetics involved. However, such advances have …

[图书][B] Heterophase polymerization: basic concepts and principles

H Hernandez, K Tauer - 2021 - taylorfrancis.com
Heterophase polymerization is a century-old technology with a wide range of relevant
industrial applications, including coatings, adhesives, rubbers, and many other specialized …

New Insights on surfactant-free styrene emulsion polymerization in The presence of sodium styrene sulfonate

L Farias-Cepeda, J Herrera-Ordonez… - Colloid and Polymer …, 2016 - Springer
The surfactant-free styrene emulsion polymerization (EP) in the presence of sodium styrene
sulfonate (NaSS) was experimentally studied. It was observed that as the NaSS content is …