Enediynes undergo a Bergman cyclization reaction to form the labile 1, 4‐didehy‐
drobenzene (p‐benzyne) biradical. The energetics of this reaction and the related Schreiner …

Garratt-Braverman cyclization has emerged as one of the simplest synthetic tool to construct
two consecutive Csingle bondC bonds leading to the formation of various important …

A novel metal-free double SO2 insertion/multicomponent bicyclization cascade of benzene-
linked 1, 7-diynes has been established by treatment with aryldiazonium tetrafluoroborates …

In this work, we present the results of extensive multiprong studies involving the fate of
deuterium-labeled substrates, EPR, trapping experiments, and LA-LDI mass spectrometry to …

Two concise strategies to synthesize oxazolidin-2-imines by cascade nucleophilic
attack/addition cyclization reactions of (Z)-2-bromo-3-phenylprop-2-en-1-ols/3-phenylprop-2 …

Development of new strategies for C–C bond formation remains in the forefront of organic
synthesis. The base-mediated rearrangement of bis-propargyl sulfones via bis-allenes …

Unsymmetrical bis-propargyl ethers and sulfonamides containing various combinations of
aryl/heteroaryl substituents at the acetylene termini were synthesized, and their reactivity …

Diradical intermediates, formed by thermolysis of alkynylcyclobutenones, can display
radical, anion, or electrophilic character because of the existence of an orbital isomer with …

A cascade (cyclo) isomerization/elimination process produces novel isoquinoline derivatives
of potential interest for pharmaceutical, biomedical, and energy-related research …

A simple strategy for the synthesis of 6H-benzo [c] chromenes and 5, 6-
dihydrophenanthridines through a judicious use of Garratt–Braverman (GB) cyclization and …