Divergent strategy in natural product total synthesis
L Li, Z Chen, X Zhang, Y Jia - Chemical reviews, 2018 - ACS Publications
The divergent total syntheses of complex natural products from a common intermediate have
attracted enormous attention in the chemical community in the past few years because it can …
attracted enormous attention in the chemical community in the past few years because it can …
Benzannulation strategies for the synthesis of carbazoles, indolocarbazoles, benzocarbazoles, and carbolines
Nitrogen-containing π-excessive aromatic heterocycles, in particular, carbazoles,
indolocarbazoles, benzocarbazoles, and carbolines have been considered the fundamental …
indolocarbazoles, benzocarbazoles, and carbolines have been considered the fundamental …
Total Synthesis of Four Classes of Daphniphyllum Alkaloids
The macrodaphniphyllamine-type, calyciphylline A-type, daphnilongeranin A-type, and
daphnicyclidin D-type alkaloids are four structurally related classes of Daphniphyllum …
daphnicyclidin D-type alkaloids are four structurally related classes of Daphniphyllum …
Total syntheses of calyciphylline A-type alkaloids (−)-10-deoxydaphnipaxianine A,(+)-daphlongamine E and (+)-calyciphylline R via late-stage divinyl carbinol …
Y Zhang, Y Chen, M Song, B Tan, Y Jiang… - Journal of the …, 2022 - ACS Publications
Among the famous Daphniphyllum alkaloids family, the calyciphylline A-type subfamily has
triggered particular interest from the organic synthesis community in recent years. Here, we …
triggered particular interest from the organic synthesis community in recent years. Here, we …
Natural product synthesis via palladium-catalyzed carbonylation
Y Bai, DC Davis, M Dai - The Journal of Organic Chemistry, 2017 - ACS Publications
Carbon monoxide is an important one-carbon source and can be incorporated in complex
molecules via various transition-metal-catalyzed carbonylation reactions. In particular …
molecules via various transition-metal-catalyzed carbonylation reactions. In particular …
Total syntheses of daphenylline, daphnipaxianine A, and himalenine D
We report the total syntheses of daphenylline (1), daphnipaxianine A (5), and himalenine D
(6), three Daphniphyllum alkaloids from the calyciphylline A subfamily. A pentacyclic …
(6), three Daphniphyllum alkaloids from the calyciphylline A subfamily. A pentacyclic …
Natural product syntheses via carbonylative cyclizations
Covering: 2000–2018 In this review, we highlight recent examples of natural product total
syntheses employing transition metal-mediated/catalyzed carbonylative cyclization …
syntheses employing transition metal-mediated/catalyzed carbonylative cyclization …
Construction of all-carbon quaternary stereocenters by catalytic asymmetric conjugate addition to cyclic enones in natural product synthesis
Z Wang - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Asymmetric catalysis for chiral compound synthesis is a rapidly growing field in modern
organic chemistry and provides enantioselective materials to meet the demands of various …
organic chemistry and provides enantioselective materials to meet the demands of various …
Total synthesis of hybridaphniphylline B
Hybridaphniphylline B (1) is a Daphniphyllum alkaloid possessing 11 rings and 19
stereocenters. Here we report the first total synthesis of 1 featuring a late-stage …
stereocenters. Here we report the first total synthesis of 1 featuring a late-stage …
[HTML][HTML] Applications of ultrasound in total synthesis of bioactive natural products: A promising green tool
S Majhi - Ultrasonics Sonochemistry, 2021 - Elsevier
Total synthesis is frequently compared to climbing as it provides a suitable route to reach a
high point from the floor, the complex natural product from simple and commercially …
high point from the floor, the complex natural product from simple and commercially …