The chemistry of actinide (An) and rare-earth metal (Ln and group 3) complexes featuring
multiple bonding interactions with main-group fragments has witnessed an enormous …

Data on the synthesis, structure, and reactivity of benzyl complexes of rare earth elements in
the oxidation state+ 3 are integrated and analyzed. A variety of methods for the synthesis of …

The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …

The half-sandwich diiodide complexes [Cp* LnI2] x (Ln= Y, Lu), obtained in high yields from
Cp* Ln (AlMe4) 2 (Cp*= C5Me5) and 2 equiv of ISiMe3, reacted with 2 equiv of potassium …

The formation and stabilization of multiple bonds between a lanthanide cation and an
anionic p-block element fragment are challenging, and only a few examples of such terminal …

A new class of cyclopentadiene-bis (oxazoline) compounds and their piano-stool-type
organometallic complexes have been prepared as catalysts for hydroamination of …

This review summarizes the progress in organo-f-element chemistry during the year 2015.
The year 2015 witnessed a slight increase of contributions in the fields of organolanthanide …

Complexes reported in the literature and potentially capable of intramolecular C—F→ Ln
interactions were analyzed. It was proposed to use the ToposPro software for structural and …

The reaction of PhN (Li) SiMe3 with 2 equiv. of dimethylcyanamide with further addition of 2
equiv. of CpTiCl3 led via Me3SiCl elimination to dinuclear titanium (IV) compound 1. The …

A new coordination mode for the hybrid scorpionate/cyclopentadienyl ligand bpzcp,[bpzcp=
2, 2-bis (3, 5-dimethylpyrazol-1-yl)-1, 1-diphenylethylcyclopentadienyl] is observed in iridium …