Electrochemistry under confinement

M Jaugstetter, N Blanc, M Kratz… - Chemical Society Reviews, 2022 - pubs.rsc.org
Although the term 'confinement'regularly appears in electrochemical literature, elevated by
continuous progression in the research of nanomaterials and nanostructures, up until today …

The 2023 terahertz science and technology roadmap

A Leitenstorfer, AS Moskalenko… - Journal of Physics D …, 2023 - iopscience.iop.org
Terahertz (THz) radiation encompasses a wide spectral range within the electromagnetic
spectrum that extends from microwaves to the far infrared (100 GHz–∼ 30 THz). Within its …

Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt

P Li, Y Jiang, Y Hu, Y Men, Y Liu, W Cai, S Chen - Nature Catalysis, 2022 - nature.com
The origin of the large kinetic pH effect in hydrogen electrocatalysis, that is, the
approximately two orders of magnitude decrease in reaction kinetics when moving from acid …

[HTML][HTML] The known-unknowns of anomalous underscreening in concentrated electrolytes

GR Elliott, KP Gregory, H Robertson, VSJ Craig… - Chemical Physics …, 2024 - Elsevier
Electrolytes are central to life and technology but lack complete understanding. Recent
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …

Linking electric double layer formation to electrocatalytic activity

MA Gebbie, B Liu, W Guo, SR Anderson… - ACS …, 2023 - ACS Publications
Electric double layers form at electrode–electrolyte interfaces and often play defining roles in
governing electrochemical reaction rates and selectivity. While double layer formation has …

In situ ammonium formation mediates efficient hydrogen production from natural seawater splitting

XL Zhang, PC Yu, SP Sun, L Shi, PP Yang… - Nature …, 2024 - nature.com
Seawater electrolysis using renewable electricity offers an attractive route to sustainable
hydrogen production, but the sluggish electrode kinetics and poor durability are two major …

Cation modifies interfacial water structures on platinum during alkaline hydrogen electrocatalysis

P Xu, R Wang, H Zhang, V Carnevale… - Journal of the …, 2024 - ACS Publications
The molecular details of an electrocatalytic interface play an essential role in the production
of sustainable fuels and value-added chemicals. Many electrochemical reactions exhibit …

Elucidation of the pH-dependent electric double layer structure at the silica/water interface using heterodyne-detected vibrational sum frequency generation …

F Wei, S Urashima, S Nihonyanagi… - Journal of the American …, 2023 - ACS Publications
The silica/water interface is one of the most abundant charged interfaces in natural
environments, and the elucidation of the water structure at the silica/water interface is …

Nature of the electrical double layer on suspended graphene electrodes

S Yang, X Zhao, YH Lu, ES Barnard… - Journal of the …, 2022 - ACS Publications
The structure of interfacial water near suspended graphene electrodes in contact with
aqueous solutions of Na2SO4, NH4Cl, and (NH4) 2SO4 has been studied using confocal …

Chemistry at Oxide/Water Interfaces: The Role of Interfacial Water

M Bin Jassar, Q Yao, F Siro Brigiano… - The Journal of …, 2024 - ACS Publications
Oxide–water interfaces host many chemical reactions in nature and industry. There, reaction
free energies markedly differ from those of the bulk. While we can experimentally and …