This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

A critical review of the state-of-the-art evidence in support of the mechanisms of
glycosylation reactions is provided. Factors affecting the stability of putative oxocarbenium …

Guidelines for O-Glycoside Formation from First Principles | ACS Central Science ACS ACS
Publications C&EN CAS Find my institution Log In ACS Central Science ACS Publications …

Synthesis of oligosaccharides has, for the past couple of decades, been greatly improved by
new methods and the ongoing development of new technologies, such as automation in …

Oligosaccharides have a variety of versatile biological effects, but unlike peptides and
oligonucleotides, investigation of the roles of oligosaccharides is not easy. Since …

The mechanism of solvent effects on the stereoselectivity of glycosylation reactions is
investigated using quantum-mechanical (QM) calculations and molecular dynamics (MD) …

The diverse presence as well as their very specific bio-responses of glycoconjugates found
in all living species requires scientists to synthesize the precise structure of these complex …

A Hydrogen bond mediated aglycone delivery (HAD) method was applied to the synthesis of
α‐glucans, which are abundant in nature, but as targets represent a notable challenge to …

The major challenge in carbohydrate synthesis is stereochemical control of glycosidic bond
formation. Different glycosylation methods have been developed that are based on the …

Ether‐protecting functions at C‐2 hydroxy groups have been found to play participating roles
in glycosylations when the reactions are conducted in nitrile solvent mixtures. The …