Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

Building on architectural principles for three-dimensional metallosupramolecular construction

MMJ Smulders, IA Riddell, C Browne… - Chemical Society …, 2013 - pubs.rsc.org
Over the last two decades the field of metallosupramolecular self-assembly has emerged as
a promising research area for the development of intricate, three-dimensional structures of …

Assessing cooperativity in supramolecular systems

LKS von Krbek, CA Schalley… - Chemical Society Reviews, 2017 - pubs.rsc.org
This tutorial review summarises different aspects of cooperativity in supramolecular
complexes. We propose a systematic categorisation of cooperativity into cooperative …

High-throughput discovery of organic cages and catenanes using computational screening fused with robotic synthesis

RL Greenaway, V Santolini, MJ Bennison… - Nature …, 2018 - nature.com
Supramolecular synthesis is a powerful strategy for assembling complex molecules, but to
do this by targeted design is challenging. This is because multicomponent assembly …

Template-directed synthesis of molecular nanorings and cages

PS Bols, HL Anderson - Accounts of chemical research, 2018 - ACS Publications
Conspectus This Account is about templates as construction tools: molecules for making
molecules. A template organizes the reactants and provides information to promote …

Multiporphyrinic cages: architectures and functions

S Durot, J Taesch, V Heitz - Chemical reviews, 2014 - ACS Publications
Since the first synthesis of cryptands and cavitands, molecular cages defined as hollow
structures enclosing a three-dimensional cavity have experienced a large development in …

Vernier template synthesis of molecular knots

Z Ashbridge, E Kreidt, L Pirvu, F Schaufelberger… - Science, 2022 - science.org
Molecular knots are often prepared using metal helicates to cross the strands. We found that
coordinatively mismatching oligodentate ligands and metal ions provides a more effective …

Cyclic polymers: synthesis, characteristics, and emerging applications

C Chen, T Weil - Nanoscale Horizons, 2022 - pubs.rsc.org
Cyclic polymers with a ring-like topology and no chain ends are a unique class of
macromolecules. In the past several decades, significant advances have been made to …

Controlling supramolecular polymerization through multicomponent self‐assembly

P Besenius - Journal of Polymer Science Part A: Polymer …, 2017 - Wiley Online Library
The self‐assembly into supramolecular polymers is a process driven by reversible non‐
covalent interactions between monomers, and gives access to materials applications …

Self-assembly of Russian doll concentric porphyrin nanorings

SAL Rousseaux, JQ Gong, R Haver… - Journal of the …, 2015 - ACS Publications
Electronic communication between concentric macrocycles with wave functions that extend
around their circumferences can lead to remarkable behavior, as illustrated by multiwalled …