Magnesium isotope fractionation in biogenic and abiogenic carbonates: implications for paleoenvironmental proxies

C Saenger, Z Wang - Quaternary Science Reviews, 2014 - Elsevier
Geochemical variations in marine biogenic carbonates that are preserved in the geological
record serve as proxies of past environmental change. However, interpreting most proxies is …

Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions

DJ DePaolo - Geochimica et cosmochimica acta, 2011 - Elsevier
A surface reaction kinetic model is developed for predicting Ca isotope fractionation and
metal/Ca ratios of calcite as a function of rate of precipitation from aqueous solution. The …

Crystallization behavior of solid solutions from aqueous solutions: An environmental perspective

M Prieto, F Heberling, RM Rodríguez-Galán… - Progress in crystal growth …, 2016 - Elsevier
Aqueous–solid solution (AQ-SS) processes have garnered increasing attention from
geochemists and environmental engineers because they play major roles in the fate and …

Sea surface temperature and salinity reconstruction from coral geochemical tracers

T Corrège - Palaeogeography, Palaeoclimatology, Palaeoecology, 2006 - Elsevier
Massive scleractinian corals secrete an aragonitic skeleton which incorporates a large array
of chemical tracers. Corals present several advantages for palaeoclimate research: they …

Element partitioning during precipitation of aragonite from seawater: A framework for understanding paleoproxies

GA Gaetani, AL Cohen - Geochimica et cosmochimica acta, 2006 - Elsevier
This study presents the results from precipitation experiments carried out to investigate the
partitioning of the alkaline earth cations Mg2+, Ca2+, Sr2+, and Ba2+ between abiogenic …

Kinetics of Mg partition and Mg stable isotope fractionation during its incorporation in calcite

V Mavromatis, Q Gautier, O Bosc, J Schott - Geochimica et Cosmochimica …, 2013 - Elsevier
Calcite growth experiments have been performed in the presence of aqueous Mg at 25° C
and 1bar pCO2 to quantify magnesium partition coefficient DMg=(Mg/Ca) solid (Mg/Ca) fluid …

Calibration of the dual clumped isotope thermometer for carbonates

J Fiebig, M Daëron, M Bernecker, W Guo… - … et Cosmochimica Acta, 2021 - Elsevier
The Δ 47 (paleo) thermometer has opened a new avenue to determine carbonate formation
temperatures independent of the oxygen isotopic composition of the fluid from which the …

Oxygen isotopic fractionation during inorganic calcite precipitation―Effects of temperature, precipitation rate and pH

M Dietzel, J Tang, A Leis, SJ Köhler - Chemical Geology, 2009 - Elsevier
Stable oxygen isotopic fractionation during inorganic calcite precipitation was
experimentally studied by spontaneous precipitation at various pH (8.3< pH< 10.5) …

Strong biological controls on Sr/Ca ratios in aragonitic marine bivalve shells

DP Gillikin, A Lorrain, J Navez… - Geochemistry …, 2005 - Wiley Online Library
It is well known that skeletal remains of carbonate secreting organisms can provide a wealth
of information about past environments. Sr/Ca ratios have been successfully used as a …

Precipitation variability in the Indian Central Himalaya during last ca. 4,000 years inferred from a speleothem record: Impact of Indian Summer Monsoon (ISM) and …

BS Kotlia, AK Singh, LM Joshi, BS Dhaila - Quaternary International, 2015 - Elsevier
We report the first high resolution stalagmite record from Indian Central Himalaya by using a
combined oxygen and carbon isotopic study spanning the last 4000 years. In addition to the …