Five-Coordinated Geometries from Molecular Structures to Solutions in Copper(II) Complexes Generated from Polydentate-N-Donor Ligands and Pseudohalides

FA Mautner, RC Fischer, A Torvisco, MM Henary… - Molecules, 2020 - mdpi.com
A novel series of mononuclear five-coordinated pseudohalido-Cu (II) complexes displaying
distorted square bipyramidal:[Cu (L1)(NCS) 2](1),[Cu (L2)(NCS) 2](2) and [Cu (L3)(NCS)] …

Coordination polymers in dicyanamido-cadmium (II) with diverse network dimensionalities

FA Mautner, PV Jantscher, RC Fischer, A Torvisco… - Crystals, 2021 - mdpi.com
The synthesis and structural characterization of six dicyanamido-cadmium (II) complexes are
reported: catena-[Cd (μ1, 3-dca)(μ1, 5-dca)(3-ampy)](1), catena-[Cd3 (μ1, 3, 5-dca) 2 (μ1, 5 …

Synthesis and characterization of four dicyanamide bridged copper (II) complexes with N2O donor tridentate Schiff bases as blocking ligands

PK Bhaumik, K Harms, S Chattopadhyay - Inorganica Chimica Acta, 2013 - Elsevier
Four copper (II) complexes [Cu (L 1)(dca)] n (1),[Cu (L 2)(dca)(H 2 O)] 2 (2),[Cu (L 3)(dca)] n
(3) and [Cu (L 4)(dca)] n (4), where HL 1= 2-[(2-aminoethylimino) methyl]-4-nitrophenol, HL …

Synthesis, crystal structures, spectral and magnetic properties of 1-D polymeric dicyanamido-metal (II) complexes

FA Mautner, M Traber, RC Fischer, SS Massoud… - Polyhedron, 2017 - Elsevier
Five new metal (II) dicyanamide (dca) complexes with 4-hydroxymethylpyridine (4-OMP) and
4-methoxypyridine (4-MOP) have been synthesized,[Co (dca) 2 (4-OMP) 2] n (1),[Cu (dca) 2 …

Syntheses, structures, thermal and luminescent properties of cadmium (II) complexes based on quinazoline and phthalazine

B Machura, I Nawrot, R Kruszynski, M Dulski - Polyhedron, 2013 - Elsevier
Six cadmium (II) compounds [Cd (Qnz) 2 (SCN) 2] n (1),[Cd (Qnz) 2 (dca) 2] n (2),[Cd (Qnz) 2
(N3) 2]} n (3),[Cd2 (μ-SCN-κ2N: S) 2 (SCN) 2 (Ptz) 4 (H2O) 2](4),[Cd (Ptz) 2 (dca) 2] n (5) …

Miscellaneous dimensional coordination polymers and luminescence emission properties of cadmium (II)-pseudohalide complexes

FA Mautner, RC Fischer, NMH Salem… - Inorganica Chimica …, 2022 - Elsevier
Two dimensional classes of coordination polymers: 2D catena-[Cd (Me 3 en)(µ 1, 5-dca)
2](1) and catena-[Cd (ampip)(μ 1, 1-N 3)(μ 1, 3-N 3) 2](2) and 1D catena-[Cd (pren)(μ 1, 1-N …

Studies on the Reaction of Iron (II) with NO in a Noncoordinating Ionic Liquid

S Begel, R Puchta, J Sutter, FW Heinemann… - Inorganic …, 2015 - ACS Publications
In an earlier study we investigated the reaction of iron (II) chloride with NO in a strongly
coordinating ionic liquid 1-ethyl-3-methylimidazolium dicyanamide [emim][dca] and showed …

Dicyanamido-metal (II) complexes. Part 6: 1D polymeric copper (II) complexes bridging by dicyanamide. Effect of copper (II) salt on the nature of the polymeric product

SS Massoud, MM Lemieux, L Le Quan, R Vicente… - Inorganica Chimica …, 2012 - Elsevier
The complexes {[Cu (L)(μ1, 5-dca)](ClO4)} n (1, L= bepza; 2, L= bedmpza) and [Cu (L)(μ1, 5-
dca)(dca)] n (3, L= bepza; 4, L= bedmpza), where dca= dicyanamide anion, bepza= bis [2-(1 …

A new nano-scale manganese (II) coordination polymer constructed from semicarbazone Schiff base and dicyanamide ligands: Synthesis, crystal structure and DFT …

S Farhadi, F Mahmoudi, J Simpson - Journal of Molecular Structure, 2016 - Elsevier
A new nano-structured Mn (II) coordination polymer [Mn (HL)(dca)(Cl)] n (1),[HL= Pyridine-2-
carbaldehyde semicarbazone, dca= dicyanamide] has been synthesized by a sonochemical …

The classic “Brown-Ring” reaction in a new medium: kinetics, mechanism, and spectroscopy of the reversible binding of nitric oxide to iron (II) in an ionic liquid

S Begel, FW Heinemann, G Stopa, G Stochel… - Inorganic …, 2011 - ACS Publications
To elucidate the applicability and properties of ionic liquids (ILs) to serve as chemical
reaction media for the activation of small molecules by transition-metal complexes, detailed …