In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

Transition metal (TM) catalyzed cross-coupling reactions are the utmost versatile and
reliable methods for the production of many industrially important fine chemicals. The …

BACKGROUND The development of useful new methods for the construction of carbon-
carbon bonds has had an impact on the many scientific disciplines (including materials …

The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

For more than 30 years, palladium has been extensively employed in the Suzuki–Miyaura
cross coupling reaction (SMCR) for the synthesis of C–C coupled products. However, Pd …

Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Since that time, the development of organonickel chemistry has led to the discovery of
several outstanding catalytic systems and powerful practical applications. 2− 5 Nickel …

The ligand-assisted palladium (Pd)-catalyzed Suzuki–Miyaura cross-coupling reaction is
one of the most attractive protocols in organic chemistry and phosphines have been …