Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

Metal–organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses

J Fonseca, T Gong, L Jiao, HL Jiang - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
The field of metal–organic frameworks (MOFs) has been incorrectly believed to be purely
crystalline. However, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF …

Metal–organic framework glass composites

R Lin, M Chai, Y Zhou, V Chen, TD Bennett… - Chemical Society …, 2023 - pubs.rsc.org
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

CoSe2 Subnanometer Belts with Se Vacancies and Ni Substitutions for the Efficient Electrosynthesis of High-Value-Added Nitriles Coupled with Hydrogen …

L Zeng, W Chen, Q Zhang, S Xu, W Zhang, F Lv… - ACS …, 2022 - ACS Publications
The electrosynthesis of organic amines to high-value-added nitriles coupled with hydrogen
generation is a highly efficient way to achieve carbon neutrality; however, the development …

Network-forming liquids from metal–Bis (acetamide) frameworks with low melting temperatures

M Liu, RD McGillicuddy, H Vuong, S Tao… - Journal of the …, 2021 - ACS Publications
Molten phases of metal–organic networks offer exciting opportunities for using coordination
chemistry principles to access liquids and glasses with unique and tunable structures and …

Glass Formation in Hybrid Organic‐Inorganic Perovskites

C Ye, LN McHugh, C Chen, SE Dutton… - Angewandte Chemie …, 2023 - Wiley Online Library
Crystalline materials have governed the development of hybrid organic‐inorganic
perovskites (HOIPs), giving rise to a variety of fascinating applications such as solar cells …

Fabrication of Super‐Sized Metal Inorganic‐Organic Hybrid Glass with Supramolecular Network via Crystallization‐Suppressing Approach

MA Ali, WMW Winters, MA Mohamed… - Angewandte Chemie …, 2023 - Wiley Online Library
Metal coordination compound (MCC) glasses [eg, metal‐organic framework (MOF) glass,
coordination polymer glass, and metal inorganic‐organic complex (MIOC) glass] are …

Functions and applications of emerging metal–organic-framework liquids and glasses

M Wang, H Zhao, B Du, X Lu, S Ding… - Chemical …, 2023 - pubs.rsc.org
Traditional metal–organic-frameworks (MOFs) have been extensively studied and applied in
various fields across chemistry, biology and engineering in the past decades. Recently, a …

Crystallization Kinetics of a Liquid-Forming 2D Coordination Polymer

C Das, T Nishiguchi, Z Fan, S Horike - Nano Letters, 2022 - ACS Publications
We investigated a mechanism of crystal melting and crystallization behavior of a two-
dimensional coordination polymer [Ag2 (L1)(CF3SO3) 2](1, L1= 4, 4 …

Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2024 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …