Fluorinated aliphatic diazirines: preparation, characterization, and model photolabeling studies
Y Kornii, O Shablykin, T Tarasiuk… - The Journal of …, 2022 - ACS Publications
The previously unknown difluoromethyl diazirines and the previously neglected
trifluoromethyl-aliphatic diazirines were synthesized and characterized. Model photolabeling …
trifluoromethyl-aliphatic diazirines were synthesized and characterized. Model photolabeling …
Microwave-Assisted Synthesis of E-Aldimines, N-Heterocycles, and H2 by Dehydrogenative Coupling of Benzyl Alcohol and Aniline Derivatives Using CoCl2 as a …
A Pal, KM Das, A Thakur - The Journal of Organic Chemistry, 2023 - ACS Publications
The acceptorless dehydrogenative coupling (ADC) between alcohols and amines to
produce imines has been achieved mostly by employing precious-metal-based complexes …
produce imines has been achieved mostly by employing precious-metal-based complexes …
Residue-selective protein C-formylation via sequential difluoroalkylation-hydrolysis
The carbonyl group is now a widely useful, nonproteinogenic functional group in chemical
biology, yet methods for its generation in proteins have relied upon either cotranslational …
biology, yet methods for its generation in proteins have relied upon either cotranslational …
Modern fluorine‐containing agrochemicals
Today, modern fluorine‐containing agrochemicals are of the utmost importance to control
weeds, insect pests, and many plant diseases and, ultimately, to ensure sustainable yields …
weeds, insect pests, and many plant diseases and, ultimately, to ensure sustainable yields …
A convenient synthesis of difluoroalkyl ethers from thionoesters using silver (I) fluoride
J Newton, D Driedger, MB Nodwell… - … A European Journal, 2019 - Wiley Online Library
Herein we report the mild and rapid fluorodesulfurization of thionoesters using only silver (I)
fluoride. This reaction demonstrates excellent functional group tolerance and complements …
fluoride. This reaction demonstrates excellent functional group tolerance and complements …
Room temperature deoxofluorination of aromatic aldehydes with XtalFluor-E under highly concentrated conditions
O Thibeault, MR Ouellet-Du Berger, M Gonay… - Organic & …, 2023 - pubs.rsc.org
The synthesis of difluoromethyl-containing compounds exploiting the deoxofluorination
reaction of aromatic aldehydes using XtalFluor-E is described. This transformation occurs at …
reaction of aromatic aldehydes using XtalFluor-E is described. This transformation occurs at …
Selective synthesis of trisubstituted pyrroles through the reactions of alkynyl Fischer carbene complexes with oxazolones
J López, I Velazco-Cabral… - Organic & …, 2020 - pubs.rsc.org
An efficient and simple synthesis of novel trisubstituted 1H-pyrroles 4a–qvia 1, 3-dipolar
cycloaddition of Δ3-trifluoromethyloxazolones 2a–d with both chromium and tungsten …
cycloaddition of Δ3-trifluoromethyloxazolones 2a–d with both chromium and tungsten …
Base‐Promoted Formylation and N‐Difluoromethylation of Azaindoles with Ethyl Bromodifluoroacetate as a Carbon Source
Y Li, N Sun, CL Zhang, M Hao - Chinese Journal of Chemistry, 2021 - Wiley Online Library
Main observation and conclusion We reported for the first time that ethyl
bromodifluoroacetate directly reacts with azaindole without transition metal catalysis to …
bromodifluoroacetate directly reacts with azaindole without transition metal catalysis to …
Asymmetric Dipyrrin and F-BODIPYs Conjugated to Terminal Alkynes and Alkenes
C Figliola, KN Robertson, S Greening… - The Journal of Organic …, 2017 - ACS Publications
An asymmetric meso-H dipyrrin featuring a conjugated terminal alkyne substituent was
converted to its corresponding difluoro boron complex, and the extent of π-conjugation was …
converted to its corresponding difluoro boron complex, and the extent of π-conjugation was …