Proudly serving the scientific community for over a century, this 97th edition of the CRC
Handbook of Chemistry and Physics is an update of a classic reference, mirroring the growth …

The bond dissociation energy (enthalpy) is also referred to as bond disruption energy, bond
energy, bond strength, or binding energy (abbreviation: BDE, BE, or D). It is defined as the …

Radical carbonylation offers potent methods for introducing carbon monoxide into organic
molecules. This feature article focuses on our current efforts to develop new strategies for …

A computer program has been developed to model and analyze the data from photoelectron
photoion coincidence (PEPICO) spectroscopy experiments. This code has been used during …

An imaging photoelectron photoion coincidence spectrometer at the vacuum ultraviolet
(VUV) beamline of the Swiss Light Source is presented and a few initial measurements are …

A composite theoretical method for accurate thermochemical kinetics, G3X-K, is described.
This method is accurate to around 0.5 kcalmol− 1 for barrier heights and 0.8 kcalmol− 1 for …

The application of 211 At to targeted cancer therapy is currently hindered by the rapid
deastatination that occurs in vivo. As the deastatination mechanism is unknown, we tackled …

The Active Thermochemical Tables (ATcT) yield 8.477±0.007 eV as the ionization energy of
the vinyl radical, which agrees with wave function theory results. The photoionization …

The thermochemistry of halocarbon species containing iodine and bromine is examined
through an extensive interplay between new Feller–Peterson–Dixon (FPD) style composite …

Aminocarbonylation of alkenyl iodides with CO and amines proceeded under heating to
produce α, β-unsaturated amides in good yields (23 examples, 71% average yield). This …