Medium-sized heterocycles are widespread among a spectrum of structurally intriguing and
biologically significant natural products and synthetic pharmaceuticals. Metal-catalyzed high …

Medium N‐heterocycles, azepines and azocines, serve as important skeletons that occurred
widely in natural products, however, due to the lack of efficient synthetic methodologies, their …

The exploration of the complex chemical diversity of bicyclo [n. 1.1] alkanes and their use as
benzene bioisosteres has garnered significant attention over the past two decades …

Abstract Bicyclo [2.1. 1] hexanes (BCHs) are becoming ever more important in drug design
and development as bridged scaffolds that provide underexplored chemical space, but are …

While cycloaddition reactions of bicyclobutanes (BCBs) have emerged as a potent method
for synthesizing (hetero-) bicyclo [n. 1.1] alkanes (usually n≤ 3), their utilization in the …

The cycloaddition reaction involving bicyclo [1.1. 0] butanes (BCBs) offers a versatile and
efficient synthetic platform for producing C (sp3)‐rich rigid bridged ring scaffolds, which act …

Ring-opening of bicyclo [1.1. 0] butanes (BCBs) is emerging as a powerful strategy for 1, 3-
difunctionalized cyclobutane synthesis. However, reported radical strain-release reactions …

Cobalt complexes of chiral pyrox ligands catalyzed enantioselective reductive couplings of
nonconjugated iododienes with aryl iodides or alkenyl bromides. The reaction enabled …

Abstract The palladium‐catalyzed asymmetric [4+ 3] cyclization of trimethylenemethane
donors with benzofuran‐derived azadienes furnishes chiral benzofuro [3, 2‐b] azepine …

The development of (4+ 3) cyclizations of vinyl aziridines, especially catalytic asymmetric
versions, is needed in organic synthesis. This report describes an iridium-catalyzed (4+ 3) …