The progress and outlook of metal single-atom-site catalysis

X Liang, N Fu, S Yao, Z Li, Y Li - Journal of the American Chemical …, 2022 - ACS Publications
Single-atom-site catalysts (SASCs) featuring maximized atom utilization and isolated active
sites have progressed tremendously in recent years as a highly prosperous branch of …

Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

Identifying and tailoring C–N coupling site for efficient urea synthesis over diatomic Fe–Ni catalyst

X Zhang, X Zhu, S Bo, C Chen, M Qiu, X Wei… - Nature …, 2022 - nature.com
Electrocatalytic urea synthesis emerged as the promising alternative of Haber–Bosch
process and industrial urea synthetic protocol. Here, we report that a diatomic catalyst with …

Rare-earth doping in nanostructured inorganic materials

B Zheng, J Fan, B Chen, X Qin, J Wang… - Chemical …, 2022 - ACS Publications
Impurity doping is a promising method to impart new properties to various materials. Due to
their unique optical, magnetic, and electrical properties, rare-earth ions have been …

Exploring the Ni 3d Orbital Unpaired Electrons Induced Polarization Loss Based on Ni Single‐Atoms Model Absorber

H Liang, G Chen, D Liu, Z Li, S Hui… - Advanced Functional …, 2023 - Wiley Online Library
Single‐atoms (SAs) strategies have been proved to be effective in modulating
electromagnetic wave (EMW) absorption, however, the establishment of a definitive …

Atomically dispersed materials: Ideal catalysts in atomic era

T Gan, D Wang - Nano Research, 2024 - Springer
Catalysts can accelerate the chemical reaction rate and effectively promote the molecules
transformation, which is of great significance in the research of chemical industry and …

Ensemble effect for single-atom, small cluster and nanoparticle catalysts

Y Guo, M Wang, Q Zhu, D Xiao, D Ma - Nature Catalysis, 2022 - nature.com
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …

Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries

X Hai, S Xi, S Mitchell, K Harrath, H Xu, DF Akl… - Nature …, 2022 - nature.com
The stabilization of transition metals as isolated centres with high areal density on suitably
tailored carriers is crucial for maximizing the industrial potential of single-atom …