A multidisciplinary investigation of the technical and environmental performances of TAML/peroxide elimination of Bisphenol A compounds from water
Y Onundi, BA Drake, RT Malecky, MA DeNardo… - Green …, 2017 - pubs.rsc.org
Designing technologies that mitigate the low-dose adverse effects of exposures to large-
volume, everyday-everywhere chemicals such as bisphenol A (BPA, 1a) requires an …
volume, everyday-everywhere chemicals such as bisphenol A (BPA, 1a) requires an …
Enhanced Treatment of Municipal Wastewater Effluents by Fe-TAML/H2O2: Efficiency of Micropollutant Abatement
Combining iron with a tetraamido-macrocyclic ligand (Fe-TAML) as a catalyst and with
hydrogen peroxide (H2O2) as the bulk oxidant is a process that has been suggested for the …
hydrogen peroxide (H2O2) as the bulk oxidant is a process that has been suggested for the …
Rapid Destruction of Tetrabromobisphenol A by Iron(III)-Tetraamidomacrocyclic Ligand/Layered Double Hydroxide Composite/H2O2 System
C Wang, J Gao, C Gu - Environmental science & technology, 2017 - ACS Publications
Iron (III)-tetraamidomacrocyclic ligand (Fe (III)-TAML) activators have received widespread
attentions for their abilities to activate hydrogen peroxide to oxidize many organic pollutants …
attentions for their abilities to activate hydrogen peroxide to oxidize many organic pollutants …
Bioinspired, multidisciplinary, iterative catalyst design creates the highest performance peroxidase mimics and the field of sustainable ultradilute oxidation catalysis …
GR Warner, Y Somasundar, KC Jansen, EZ Kaaret… - ACS …, 2019 - ACS Publications
Oxidation catalysts called NewTAMLs, macrocyclic complexes with TAML carbonamido-N
donors replaced by more nucleophile-resistant binders, sulfonamido-N, for example,[Fe {4 …
donors replaced by more nucleophile-resistant binders, sulfonamido-N, for example,[Fe {4 …
The Mechanism of Formation of Active Fe-TAMLs Using HClO Enlightens Design for Maximizing Catalytic Activity at Environmentally Optimal, Circumneutral pH
P Pal, MC Schafer, MP Hendrich, AD Ryabov… - Inorganic …, 2023 - ACS Publications
Fe-TAML/peroxide catalysis provides simple, powerful, ultradilute approaches for removing
micropollutants from water. The typically rate-determining interactions of H2O2 with Fe …
micropollutants from water. The typically rate-determining interactions of H2O2 with Fe …
Unifying evaluation of the technical performances of iron-tetra-amido macrocyclic ligand oxidation catalysts
MA DeNardo, MR Mills, AD Ryabov… - Journal of the American …, 2016 - ACS Publications
The main features of iron-tetra-amido macrocyclic ligand complex (a sub-branch of TAML)
catalysis of peroxide oxidations are rationalized by a two-step mechanism: FeIII+ H2O2→ …
catalysis of peroxide oxidations are rationalized by a two-step mechanism: FeIII+ H2O2→ …
TAML/H2O2 Oxidative Degradation of Metaldehyde: Pursuing Better Water Treatment for the Most Persistent Pollutants
The extremely persistent molluscicide, metaldehyde, widely used on farms and gardens, is
often detected in drinking water sources of various countries at concentrations of regulatory …
often detected in drinking water sources of various countries at concentrations of regulatory …
Reactivity and Operational Stability of N‐Tailed TAMLs through Kinetic Studies of the Catalyzed Oxidation of Orange II by H2O2: Synthesis and X‐ray Structure of an N …
GR Warner, MR Mills, C Enslin… - … A European Journal, 2015 - Wiley Online Library
The catalytic activity of the N‐tailed (“biuret”) TAML (tetraamido macrocyclic ligand)
activators [Fe {4‐XC6H3‐1, 2‐(NCOCMe2NCO) 2NR} Cl] 2−(3; N atoms in boldface are …
activators [Fe {4‐XC6H3‐1, 2‐(NCOCMe2NCO) 2NR} Cl] 2−(3; N atoms in boldface are …
Advancing the Sustainability of the Pharmaceutical Industry: TAML/Peroxide Destroys Trace Pharmaceuticals where Unprecedented Efficiencies Increase with …
X Ma, CR Johnson, MC Schafer… - ACS Sustainable …, 2024 - ACS Publications
Trace pharmaceuticals released from urban wastewater plants can devastate aquatic life,
while cost limits all known technically effective removal technologies to larger wealthier …
while cost limits all known technically effective removal technologies to larger wealthier …
Homogeneous catalysis under ultradilute conditions: TAML/NaClO oxidation of persistent metaldehyde
TAML activators enable homogeneous oxidation catalysis where the catalyst and substrate
(S) are ultradilute (pM–low μM) and the oxidant is very dilute (high nM–low mM). Water …
(S) are ultradilute (pM–low μM) and the oxidant is very dilute (high nM–low mM). Water …