Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Near‐Infrared Light‐Induced Reversible Deactivation Radical Polymerization: Expanding Frontiers in Photopolymerization

Z Wu, C Boyer - Advanced Science, 2023 - Wiley Online Library
Photoinduced reversible deactivation radical polymerization (photo‐RDRP) or photoinduced
controlled/living radical polymerization has emerged as a versatile and powerful technique …

Persistent Radical Anions: Efficient Catalysts for Iodine-Mediated Reversible-Deactivation Radical Polymerization Driven by NIR LED Light

H Zhao, G Bian, X Xu, R Liu, W He, L Zhang… - …, 2023 - ACS Publications
Developing new catalysts with obvious advantages than existing ones is charming but very
challenging for near infrared (NIR)-photocontrolled reversible-deactivation radical …

Recent development in halogen-bonding-catalyzed living radical polymerization

CG Wang, AML Chong, HM Pan, J Sarkar, XT Tay… - Polymer …, 2020 - pubs.rsc.org
Halogen bonding (XB) has been used to catalyze organic reactions and polymerizations,
which is an emerging research area. Reversible complexation mediated polymerization …

Enhancing Ultrasound-Assisted Iodine-Mediated Reversible-Deactivation Radical Polymerization by Piezoelectric Nanoparticles

Z Ren, C Ding, R Ding, J Wang, Z Li, R Tan… - ACS Macro …, 2023 - ACS Publications
The development of mechanochemical tools for regulating the polymerization process has
received an increasing amount of attention in recent years. Herein, we report the example of …

Photocontrolled Iodine‐Mediated Reversible‐Deactivation Radical Polymerization: Solution Polymerization of Methacrylates by Irradiation with NIR LED Light

C Tian, P Wang, Y Ni, L Zhang… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract Herein, near‐infrared (NIR) photocontrolled iodide‐mediated reversible‐
deactivation radical polymerization (RDRP) of methacrylates, without an external …

Polymer dispersity control by organocatalyzed living radical polymerization

X Liu, CG Wang, A Goto - Angewandte Chemie International …, 2019 - Wiley Online Library
Molecular weight distribution of polymers, termed dispersity (Đ), is a fundamental parameter
for determining polymer material properties. This paper reports a novel approach for …

Iodine-mediated reversible-deactivation radical polymerization: a powerful strategy for polymer synthesis

Y Ni, L Zhang, Z Cheng, X Zhu - Polymer Chemistry, 2019 - pubs.rsc.org
Nowadays, well-defined polymers can be easily obtained through different techniques
benefitting from the tremendous progress achieved in reversible-deactivation radical …

Reversible complexation mediated polymerization: an emerging type of organocatalytically controlled radical polymerization

ZH Chen, XY Wang, Y Tang - Polymer Chemistry, 2022 - pubs.rsc.org
As a newly developed approach of controlled radical polymerization (CRP), reversible
complexation mediated polymerization (RCMP) was established in 2011 by Goto et al …

Spotting trends in organocatalyzed and other organomediated (de) polymerizations and polymer functionalizations

M Valle, M Ximenis, X Lopez de Pariza… - Angewandte Chemie …, 2022 - Wiley Online Library
Organocatalysis has evolved into an effective complement to metal‐or enzyme‐based
catalysis in polymerization, polymer functionalization, and depolymerization. The ease of …