DA Kuznetsov, TA Bazhenova, IV Fedyanin… - Dalton …, 2016 - pubs.rsc.org
A series of novel cluster compounds comprising molybdenum in a low valence state was synthesized by means of a disproportionation of the dimeric compound [Mo+ 42Cl4 (OCH3) …
DA Kuznetsov, NV Kovaleva, IV Fedyanin… - Polyhedron, 2015 - Elsevier
The MoCl 5 methanolysis reaction, in the presence of basic agents providing weakly alkaline media, leads to the formation of a Mo–Mo triply bridged anionic dimeric complex …
DA Kuznetsov, IV Fedyanin… - European Journal of …, 2015 - Wiley Online Library
Abstract The rare Mo= Mo double‐bonded dimeric alkoxide complex [Mo2Cl4 (OCH3) 4 (CH3OH) 2](1) was prepared by the simple methanolysis reaction of [MoCl4 (CH3CN) 2]. It …
Understanding the chemistry of high valent metals stands to open the door to a new realm of chemical transformations. Unfortunately, a relative lack of research into chemical processes …
Полиядерные комплексы переходных металлов являются ключевыми компонентами многих биологических (ферментативных) и синтетических каталитических систем …