A family of titanium complexes with catechol ligands: structural investigation and catalytic application

TA Bazhenova, NV Kovaleva, GV Shilov… - European Journal of …, 2016 - Wiley Online Library
Four new titanium catecholate complexes–[Ti2 (Cat) 2 (CatH) 2 (OCH3) 2 (CH3OH) 2](1;
Cat= C6H4O22–),[Ti2 (4tBuCat) 4 (CH3OH) 2]· 2CH3OH (2· 2CH3OH; 4tBuCat=[4‐t‐C4H9 …

Tri-, tetra-, and hexanuclear mixed-valence molybdenum clusters: structural diversity and catalysis of acetylene hydrogenation

DA Kuznetsov, TA Bazhenova, IV Fedyanin… - Dalton …, 2016 - pubs.rsc.org
A series of novel cluster compounds comprising molybdenum in a low valence state was
synthesized by means of a disproportionation of the dimeric compound [Mo+ 42Cl4 (OCH3) …

Base promoted successive dealkylation steps of molybdenum alkoxides leading to a row of novel 1D and 2D polymeric frameworks of potassium–molybdenum …

DA Kuznetsov, NV Kovaleva, IV Fedyanin… - Polyhedron, 2015 - Elsevier
The MoCl 5 methanolysis reaction, in the presence of basic agents providing weakly
alkaline media, leads to the formation of a Mo–Mo triply bridged anionic dimeric complex …

Developing Pathways to the Synthesis of Low‐Valence Molybdenum Methoxides: Preparation, Characterization, and Redox Chemistry of Dimeric and Tetrameric …

DA Kuznetsov, IV Fedyanin… - European Journal of …, 2015 - Wiley Online Library
Abstract The rare Mo= Mo double‐bonded dimeric alkoxide complex [Mo2Cl4 (OCH3) 4
(CH3OH) 2](1) was prepared by the simple methanolysis reaction of [MoCl4 (CH3CN) 2]. It …

Investigations of High Valent Metal Reactivity Using the Ligand Donor Parameter

BS Billow - 2018 - search.proquest.com
Understanding the chemistry of high valent metals stands to open the door to a new realm of
chemical transformations. Unfortunately, a relative lack of research into chemical processes …

[PDF][PDF] ПОЛИЯДЕРНЫЕ МЕТОКСИДНЫЕ КОМПЛЕКСЫ МОЛИБДЕНА В РАЗЛИЧНЫХ СТЕПЕНЯХ ОКИСЛЕНИЯ–КОМПОНЕНТЫ КАТАЛИТИЧЕСКИХ …

ДА Кузнецов - 2015 - 93.180.44.144
Полиядерные комплексы переходных металлов являются ключевыми компонентами
многих биологических (ферментативных) и синтетических каталитических систем …