Electronic Structure Design of Transition Metal-Based Catalysts for Electrochemical Carbon Dioxide Reduction

L Guo, J Zhou, F Liu, X Meng, Y Ma, F Hao, Y Xiong… - ACS …, 2024 - ACS Publications
With the increasingly serious greenhouse effect, the electrochemical carbon dioxide
reduction reaction (CO2RR) has garnered widespread attention as it is capable of …

Stereoselective formation of boron-stereogenic organoboron derivatives

A Abdou-Mohamed, C Aupic, C Fournet… - Chemical Society …, 2023 - pubs.rsc.org
Four-coordinate organoboron derivatives present interesting chemical, physical, biological,
electronical, and optical properties. Given the increasing demand for the synthesis of smart …

Thermally robust and highly active pcp cobalt (II) catalyst for linear-selective hydroboration of terminal and internal olefins

J Liu, J Du, F Yu, L Gan, G Liu, Z Huang - ACS Catalysis, 2023 - ACS Publications
We report the design and synthesis of cobalt complexes of L2X-type ligands for olefin
hydroboration guided by the consideration of catalyst stability. Among the series of PCP …

Transition-Metal-Based Nanozymes: Synthesis, Mechanisms of Therapeutic Action, and Applications in Cancer Treatment

Q Fu, C Wei, M Wang - ACS nano, 2024 - ACS Publications
Cancer, as one of the leading causes of death worldwide, drives the advancement of cutting-
edge technologies for cancer treatment. Transition-metal-based nanozymes emerge as …

A Unified Synthetic Approach to the Pleurotin Natural Products

Y Gao, Q Xia, A Zhu, W Mao, Y Mo… - Journal of the …, 2024 - ACS Publications
The asymmetric total syntheses of four pleurotin natural products, namely,(−)-pleurotin,(+)-
leucopleurotin,(+)-leucopleurotinic acid, and (+)-dihydropleurotinic acid, were described in a …

Iridium‐Catalyzed Remote Site‐Switchable Hydroarylation of Alkenes Controlled by Ligands

F Li, Y Luo, J Ren, Q Yuan, D Yan… - Angewandte …, 2023 - Wiley Online Library
An iridium‐catalyzed remote site‐switchable hydroarylation of alkenes was reported,
delivering the products functionalized at the subterminal methylene and terminal methyl …

Enantioconvergent Hydroboration of E/Z-Mixed Trisubstituted Alkenes

Y Bao, C Zheng, K Xiong, C Hu, P Lu… - Journal of the …, 2024 - ACS Publications
The lack of mode for chirality recognition makes it particularly challenging to carry out
asymmetric transformations on E/Z-mixed minimally functionalized trisubstituted alkenes …

Metallaphotoredox-Catalyzed Three-Component Asymmetric Cross-Electrophile Coupling for Chiral Boronate Synthesis

X Li, Y Hu, Z Huang, S Zhu, FL Qing, L Chu - ACS Catalysis, 2024 - ACS Publications
Here, we report a photoredox and nickel-catalyzed cross-electrophile coupling strategy for
the asymmetric three-component 1, 2-alkylarylation of vinyl boronates with (hetero) aryl …

Rhodium-Catalyzed Double Hydroboration of Quinolines

R Wang, S Park - ACS Catalysis, 2023 - ACS Publications
Selective double hydroelementation of N-heteroarenes can be one of the most
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …

Asymmetric dihydroboration of allenes enabled by ligand relay catalysis

Y Lei, Y Kong, ZQ Rong, W Zhao - Nature Communications, 2024 - nature.com
Catalytic asymmetric hydroboration of unsaturated bonds has been recognized as the most
straightforward method for the construction of chiral organoboron compounds. Although …