Electronic structure elucidation in oxidized metal–salen complexes

RM Clarke, K Herasymchuk, T Storr - Coordination Chemistry Reviews, 2017 - Elsevier
Salen ligands are ubiquitous in inorganic chemistry with utility in applications ranging from
materials to catalysis. Additionally, salen ligands have the potential for redox-activity due to …

Alkane and alkene oxidation reactions catalyzed by nickel (II) complexes: Effect of ligand factors

M Sankaralingam, M Balamurugan… - Coordination Chemistry …, 2020 - Elsevier
Targeting selective hydroxylation under mild conditions of saturated hydrocarbons has
become a challenging and exciting scientific area that has drawn larger attention in recent …

Rational design of first-row transition metal complexes as the catalysts for oxidation of arenes: a homogeneous approach

A Rajeev, M Balamurugan, M Sankaralingam - ACS Catalysis, 2022 - ACS Publications
Researchers have always been intrigued by one-step selective hydroxylation of aromatic
compounds since achieving adequate selectivity toward the target product and avoiding …

Biological activity of copper porphyrins

A Das, TP Mohammed, M Sankaralingam - Coordination Chemistry …, 2024 - Elsevier
The great possibility of synthetic modifications available in different aspects has elevated
porphyrins as an appealing candidate for a plethora of applications. Accordingly, changes in …

Aromatic C− H hydroxylation reactions with hydrogen peroxide catalyzed by bulky Manganese complexes

E Masferrer‐Rius, M Borrell, M Lutz… - Advanced Synthesis …, 2021 - Wiley Online Library
The oxidation of aromatic substrates to phenols with H2O2 as a benign oxidant remains an
ongoing challenge in synthetic chemistry. Herein, we successfully achieved to catalyze …

Selective oxygenation of cyclohexene by dioxygen via an iron (V)-oxo complex-autocatalyzed reaction

M Sankaralingam, YM Lee, W Nam… - Inorganic …, 2017 - ACS Publications
An iron complex with a tetraamido macrocyclic ligand,[(TAML) FeIII]−, was found to be an
efficient and selective catalyst for allylic oxidation of cyclohexene by dioxygen (O2); cyclohex …

Mononuclear copper (ii) Schiff base complexes as effective models for phenoxazinone synthase

AS Thennarasu, TP Mohammed… - New Journal of …, 2022 - pubs.rsc.org
A series of structurally related mononuclear copper (II) complexes of type [Cu (L)(SCN)] 1–3
and [Cu (L3)(N3)] 4 containing tridentate Schiff base (N2O) ligands (L1 (H)–L3 (H)), such as …

Ring-opening polymerization of rac-lactide mediated by tetrametallic lithium and sodium diamino-bis (phenolate) complexes

D Alhashmialameer, N Ikpo, J Collins, LN Dawe… - Dalton …, 2015 - pubs.rsc.org
Lithium and sodium compounds supported by tetradentate amino-bis (phenolato)
ligands,[Li2 (N2O2BuBuPip)](1),[Na2 (N2O2BuBuPip)](2)(where [N2O2BuBuPip]= 2, 2′-N …

Novel nickel (II) complexes of sterically modified linear N4 ligands: effect of ligand stereoelectronic factors and solvent of coordination on nickel (II) spin-state and …

M Sankaralingam, P Vadivelu, M Palaniandavar - Dalton Transactions, 2017 - pubs.rsc.org
A series of Ni (II) complexes of the types [Ni (L)(CH3CN) 2](BPh4) 21–3, 5 and [Ni
(L4)](BPh4) 24, where L= N, N′-bis (2-pyrid-2-ylmethyl)-1, 4-diazepane (L1), N-(6 …

Reactivities of high valent manganese-oxo porphyrins in aqueous medium

TP Mohammed, M Sankaralingam - Tetrahedron, 2022 - Elsevier
The endurance of intermediate species at normal conditions and its relevance in undergoing
myriads of oxidative catalytic processes place manganese-oxo intermediates in the limelight …