Operando scanning electrochemical probe microscopy during electrocatalysis

C Santana Santos, BN Jaato, I Sanjuán… - Chemical …, 2023 - ACS Publications
Scanning electrochemical probe microscopy (SEPM) techniques can disclose the local
electrochemical reactivity of interfaces in single-entity and sub-entity studies. Operando …

Modeling Operando Electrochemical CO2 Reduction

F Dattila, RR Seemakurthi, Y Zhou, N López - Chemical Reviews, 2022 - ACS Publications
Since the seminal works on the application of density functional theory and the
computational hydrogen electrode to electrochemical CO2 reduction (eCO2R) and …

Mechanism of CN bonds formation in electrocatalytic urea production revealed by ab initio molecular dynamics simulation

X Liu, Y Jiao, Y Zheng, M Jaroniec, SZ Qiao - Nature Communications, 2022 - nature.com
Electrosynthesis of urea from CO2 and NOX provides an exceptional opportunity for human
society, given the increasingly available renewable energy. Urea electrosynthesis is …

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

S Nitopi, E Bertheussen, SB Scott, X Liu… - Chemical …, 2019 - ACS Publications
To date, copper is the only heterogeneous catalyst that has shown a propensity to produce
valuable hydrocarbons and alcohols, such as ethylene and ethanol, from electrochemical …

The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction

RM Arán-Ais, F Scholten, S Kunze, R Rizo… - Nature Energy, 2020 - nature.com
The efficient electrochemical conversion of CO2 provides a route to fuels and feedstocks.
Copper catalysts are well-known to be selective to multicarbon products, although the role …

Designing copper‐based catalysts for efficient carbon dioxide electroreduction

Y Wang, J Liu, G Zheng - Advanced Materials, 2021 - Wiley Online Library
The electroreduction of carbon dioxide (CO2) has been emerging as a high‐potential
approach for CO2 utilization using renewables. When copper (Cu) based catalysts are used …

Surface and interface control in nanoparticle catalysis

C Xie, Z Niu, D Kim, M Li, P Yang - Chemical reviews, 2019 - ACS Publications
The surface and interfaces of heterogeneous catalysts are essential to their performance as
they are often considered to be active sites for catalytic reactions. With the development of …

Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction

J Vavra, GPL Ramona, F Dattila, A Kormányos… - Nature Catalysis, 2024 - nature.com
Understanding metal surface reconstruction is of the utmost importance in electrocatalysis,
as this phenomenon directly affects the nature of available active sites. However, its dynamic …

CO2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface

CT Dinh, T Burdyny, MG Kibria, A Seifitokaldani… - Science, 2018 - science.org
Carbon dioxide (CO2) electroreduction could provide a useful source of ethylene, but low
conversion efficiency, low production rates, and low catalyst stability limit current systems …

The role of electrode wettability in electrochemical reduction of carbon dioxide

M Li, MN Idros, Y Wu, T Burdyny, S Garg… - Journal of Materials …, 2021 - pubs.rsc.org
The electrochemical reduction of carbon dioxide (CO2RR) requires access to ample
gaseous CO2 and liquid water to fuel reactions at high current densities for industrial-scale …