[HTML][HTML] Glucosinolate structural diversity, identification, chemical synthesis and metabolism in plants

I Blažević, S Montaut, F Burčul, CE Olsen, M Burow… - Phytochemistry, 2020 - Elsevier
The glucosinolates (GSLs) is a well-defined group of plant metabolites characterized by
having an S-β-d-glucopyrano unit anomerically connected to an O-sulfated (Z) …

Glucosinolate structures in evolution

N Agerbirk, CE Olsen - Phytochemistry, 2012 - Elsevier
By 2000, around 106 natural glucosinolates (GSLs) were probably documented. In the past
decade, 26 additional natural GSL structures have been elucidated and documented …

Glucosinolates, structures and analysis in food

DB Clarke - Analytical methods, 2010 - pubs.rsc.org
Glucosinolates (GLS) are sulfur rich, anionic secondary metabolites found principally in the
plant order Brassicales. This review focuses on identifying the range of GLS structures …

Glucosinolates: Natural occurrence, biosynthesis, accessibility, isolation, structures, and biological activities

VPT Nguyen, J Stewart, M Lopez, I Ioannou, F Allais - Molecules, 2020 - mdpi.com
Glucosinolates (GSLs) are secondary plant metabolites abundantly found in plant order
Brassicales. GSLs are constituted by an S-β-d-glucopyrano unit anomerically connected to …

Brassicaceae: A rich source of health improving phytochemicals

P Avato, MP Argentieri - Phytochemistry reviews, 2015 - Springer
Abstract Brassicaceae Burnett (syn. Cruciferae AL de Jussieu) include many important
economic plants used as edible or ornamental which are commonly known as the “mustard” …

Indole glucosinolate breakdown and its biological effects

N Agerbirk, M De Vos, JH Kim, G Jander - Phytochemistry Reviews, 2009 - Springer
Most species in the Brassicaceae produce one or more indole glucosinolates. In addition to
the parent indol-3-ylmethylglucosinolate (IMG), other commonly encountered indole …

Catalytic asymmetric hydroxylation of oxindoles by molecular oxygen using a phase-transfer catalyst

D Sano, K Nagata, T Itoh - Organic Letters, 2008 - ACS Publications
The highly enantioselective catalytic hydroxylation of 3-substituted oxindoles was achieved
by using a phase-transfer catalyst with molecular oxygen as an oxidant. The product then …

Lambert salt-initiated development of Friedel–crafts reaction on isatin to access distinct derivatives of oxindoles

J Khan, A Tyagi, N Yadav, R Mahato… - The Journal of Organic …, 2021 - ACS Publications
Herein, a mild metal-free and efficacious route for the synthesis of biologically important 3-
aryl oxindole derivatives is described. Using Lambert salt-initiated hydroarylation of isatin, a …

[HTML][HTML] Enantioselective Allylation, Crotylation and Reverse Prenylation of Substituted Isatins via Iridium Catalyzed CC Bond Forming Transfer Hydrogenation

J Itoh, SB Han, MJ Krische - Angewandte Chemie (International ed …, 2009 - ncbi.nlm.nih.gov
Transfer hydrogenation of substituted isatins in the presence of allyl acetate, α-methyl allyl
acetate or 1, 1,-dimethylallene employing an ortho-cyclometallated iridium catalyst modified …

Rhodium-catalyzed addition of arylboronic acids to isatins: An entry to diversity in 3-aryl-3-hydroxyoxindoles

PY Toullec, RBC Jagt, JG de Vries, BL Feringa… - Organic …, 2006 - ACS Publications
A general method for the catalytic 1, 2-addition of aryl and alkenyl boronic acids to isatins is
described using a rhodium (I)/triphenylphosphite catalyst. The application of this …