Electrode materials in modern organic electrochemistry

DM Heard, AJJ Lennox - Angewandte Chemie International …, 2020 - Wiley Online Library
The choice of electrode material is critical for achieving optimal yields and selectivity in
synthetic organic electrochemistry. The material imparts significant influence on the kinetics …

Toward greener nanosynthesis

JA Dahl, BLS Maddux, JE Hutchison - Chemical reviews, 2007 - ACS Publications
During the past decade, scientists have developed techniques for synthesizing and
characterizing many new materials with at least one dimension on the nanoscale, including …

Organic electrosynthesis towards sustainability: fundamentals and greener methodologies

S Cembellín, B Batanero - The Chemical Record, 2021 - Wiley Online Library
The adoption of new measures that preserve our environment, on which our survival
depends, is a necessity. Electro‐organic processes are sustainable per se, by producing the …

[HTML][HTML] Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids

R Matthessen, J Fransaer… - Beilstein journal of …, 2014 - beilstein-journals.org
The near-unlimited availability of CO 2 has stimulated a growing research effort in creating
value-added products from this greenhouse gas. This paper presents the trends on the most …

Electrohalogenation of organic compounds

MR Scheide, CR Nicoleti, GM Martins… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Herein, we present an overview of recent advances in the electrochemical halogenation of
organic compounds. Halogen-containing compounds are essential building blocks for post …

High-throughput electrochemistry: state of the art, challenges, and perspective

AG Wills, S Charvet, C Battilocchio… - … Process Research & …, 2021 - ACS Publications
Electrochemical transformations involve complex parameter interactions, ranging from
universal chemistry variables such as solvent and reagents to specialist factors including …

Integrated electrochemical–chemical oxidation mediated by alkoxysulfonium ions

Y Ashikari, T Nokami, J Yoshida - Journal of the American …, 2011 - ACS Publications
Generation of carbocations by the “cation pool” method followed by reaction with dimethyl
sulfoxide (DMSO) gave the corresponding alkoxysulfonium ions. Alkoxysulfonium ions could …

Gas diffusion electrode as novel reaction system for an electro-enzymatic process with chloroperoxidase

T Krieg, S Hüttmann, KM Mangold, J Schrader… - Green …, 2011 - pubs.rsc.org
The versatile enzyme chloroperoxidase was used in a new reaction system, based on a gas
diffusion electrode, for enzymatic chlorinations, sulfoxidations and oxidations. This is the first …

Mechanistic Studies on the Anodic Functionalization of Alkenes Catalyzed by Diselenides

M Wilken, S Ortgies, A Breder, I Siewert - ACS Catalysis, 2018 - ACS Publications
Herein, we present a detailed kinetic and thermodynamic analysis of the anodic allylic
esterification of alkenes as well as the bulk application of the anodic amination and …

A continuous-flow electrochemical Taylor vortex reactor: a laboratory-scale high-throughput flow reactor with enhanced mixing for scalable electrosynthesis

A Love, DS Lee, G Gennari… - … Process Research & …, 2021 - ACS Publications
We report the development of a small footprint continuous electrochemical Taylor vortex
reactor capable of processing kilogram quantities of material per day. This report builds …