Photochemical action plots reveal the fundamental mismatch between absorptivity and photochemical reactivity

SL Walden, JA Carroll, AN Unterreiner… - Advanced …, 2024 - Wiley Online Library
Over the last years, the authors' laboratory has employed monochromatic tuneable laser
systems to reveal a fundamental mismatch between the absorptivity of a chromophore and …

A review on photochemical effects of common plastics and their related applications

Z Huang, H Wang - Journal of Polymer Science, 2024 - Wiley Online Library
The photochemical effects of plastics refer to a series of photochemical reactions of plastics
under certain illumination conditions. In order to help researchers understand the research …

Different timescales during ultrafast stilbene isomerization in the gas and liquid phases revealed using time-resolved photoelectron spectroscopy

C Wang, MDJ Waters, P Zhang, J Suchan… - Nature …, 2022 - nature.com
Directly contrasting ultrafast excited-state dynamics in the gas and liquid phases is crucial to
understanding the influence of complex environments. Previous studies have often relied on …

Time-Resolved X-ray Photoelectron Spectroscopy: Ultrafast Dynamics in CS2 Probed at the S 2p Edge

I Gabalski, F Allum, I Seidu, M Britton… - The journal of …, 2023 - ACS Publications
Recent developments in X-ray free-electron lasers have enabled a novel site-selective
probe of coupled nuclear and electronic dynamics in photoexcited molecules, time-resolved …

Tracking the ultraviolet-induced photochemistry of thiophenone during and after ultrafast ring opening

S Pathak, LM Ibele, R Boll, C Callegari… - Nature …, 2020 - nature.com
Photoinduced isomerization reactions lie at the heart of many chemical processes in nature.
The mechanisms of such reactions are determined by a delicate interplay of coupled …

Ultrafast electronic relaxation pathways of the molecular photoswitch quadricyclane

KD Borne, JC Cooper, MNR Ashfold, J Bachmann… - Nature Chemistry, 2024 - nature.com
The light-induced ultrafast switching between molecular isomers norbornadiene and
quadricyclane can reversibly store and release a substantial amount of chemical energy …

Conical-intersection dynamics and ground-state chemistry probed by extreme-ultraviolet time-resolved photoelectron spectroscopy

A von Conta, A Tehlar, A Schletter, Y Arasaki… - Nature …, 2018 - nature.com
Time-resolved photoelectron spectroscopy (TRPES) is a useful approach to elucidate the
coupled electronic-nuclear quantum dynamics underlying chemical processes, but has …

X-ray induced Coulomb explosion imaging of transient excited-state structural rearrangements in CS2

J Unwin, F Allum, M Britton, I Gabalski… - Communications …, 2023 - nature.com
Structural imaging of transient excited-state species is a key goal of molecular physics,
promising to unveil rich information about the dynamics underpinning photochemical …

The value of different experimental observables: a transient absorption study of the ultraviolet excitation dynamics operating in nitrobenzene

SW Crane, M Garrow, PD Lane… - The Journal of …, 2023 - ACS Publications
Excess energy redistribution dynamics operating in nitrobenzene under hexane and
isopropanol solvation were investigated using ultrafast transient absorption spectroscopy …

Electronic coherence in ultrafast X-ray scattering from molecular wave packets

M Simmermacher, NE Henriksen, KB Møller… - Physical review …, 2019 - APS
Simulations of nonresonant ultrafast x-ray scattering from a molecular wave packet in H 2
are used to examine and classify the components that contribute to the total scattering …