This article surveys the empirical information which originated both by laboratory
experiments and by computational simulations, and expands previous understanding of the …

Advances in the understanding of the dependence of reaction rates from temperature, as
motivated from progress in experiments and theoretical tools (eg, molecular dynamics), are …

The present perspective review focuses on the role of the precursor state, controlling the
dynamical evolution of elementary processes, whose structure and stability are often difficult …

To account for frequently documented low-temperature deviations from Arrhenius rate law,
the proposed expansion of inverse activation energy against inverse temperature is shown …

A formulation is presented for the application of tools from quantum chemistry and transition‐
state theory to phenomenologically cover cases where reaction rates deviate from Arrhenius …

A three dimensional potential energy surface for the F+ H 2→ HF+ H reaction has been
computed by the spin unrestricted coupled cluster method with singles, doubles, triples, and …

Activation energies Ea calculated as the negative of the logarithmic derivatives of rate
constants with respect to the inverse of absolute temperature T, are presented for three …

Among four-atom processes, the reaction OH+ HBr→ H2O+ Br is one of the most studied
experimentally: its kinetics has manifested an unusual anti-Arrhenius behavior, namely, a …

The He + |${\rm H}_2^+$|H2+ → HeH+ + H reaction: Ab initio studies of the potential energy
surface, benchmark time-independent quantum dynamics in an extended energy range and …

For the reaction between F and HD, giving HF+ D and DF+ H, the rate constants, obtained
from rigorous quantum scattering calculations at temperatures ranging from 350 K down to …