Abstract (Pentamethylcyclopentadienyl) rhodium (RhCp*)‐catalyzed C H transformations
have emerged as a prosperous field in C H bond activation. Recent advances in this area …

Transition‐metal‐catalyzed electrophilic amination has been developed into a powerful tool
for C− N bond construction. So far, O‐benzoylhydroxylamines are the most widely used …

Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

A novel Rh (III)-catalyzed C–H bond amination with the simultaneous release of a formyl
group at distal positions is realized employing anthranil as a new type of C–H amination …

A CuCl/(R, R)-Ph-BPE-catalyzed enantioselective formal hydroamination of oxa-and
azabicyclic alkenes with polymethylhydrosiloxane (PMHS) and O-benzoylhydroxylamines …

Here a new, mild and versatile method for one-pot cascade synthesis of diverse N-
methoxyisoquinolinediones via Rh (III)-catalyzed regioselective carbenoid insertion C–H …

Ligand development for rhodium (III)‐catalyzed C− H activation reactions has largely been
limited to cyclopentadienyl (Cp) based scaffolds. 2‐Methylquinoline has now been identified …

The amidation reactions of 8-methylquinolines with azides catalyzed by a cationic rhodium
(III) complex proceed efficiently to give quinolin-8-ylmethanamine derivatives in good yields …

Arene amination is achieved by site-selective C–H zincation followed by copper-catalyzed
coupling with O-benzoylhydroxylamines under mild conditions. Key to this success is ortho …

Abstract 2, 4, 6‐Trimethoxypyridine is identified as an efficient ligand for promoting a Pd‐
catalyzed ortho‐C H amination of both benzamides and triflyl‐protected benzylamines …