Water oxidation is the primary reaction of both natural and artificial photosynthesis.
Developing active and robust water oxidation catalysts (WOCs) is the key to constructing …

Abstract The 2-His-1-carboxylate facial triad is a widely used scaffold to bind the iron center
in mononuclear nonheme iron enzymes for activating dioxygen in a variety of oxidative …

This paper investigated the oxidation of recalcitrant micropollutants [ie, atenolol (ATL),
flumequine, aspartame, and diatrizoic acid] by combining ferrate (VI)(FeVIO42–, FeVI) with a …

The reaction between Fe2+ and HClO constitutes a promising advanced oxidation process
(AOP) for removing pollutants from wastewater, and• OH has been considered the dominant …

This paper presents an accelerated ferrate (VI)(FeVIO42–, FeVI) oxidation of contaminants
in 30 s by adding one-electron and two-electron transfer reductants (R (1) and R (2)). An …

Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …

TAML activators of peroxides are iron (III) complexes. The ligation by four deprotonated
amide nitrogens in macrocyclic motifs is the signature of TAMLs where the macrocyclic …

There are mechanistic dichotomies with regard to the formation, electronic structures and
reaction mechanisms of metal–oxygen intermediates, since these metal–oxygen species …

Destruction of pharmaceuticals excreted in urine can be an efficient approach to eliminate
these environmental pollutants. However, urine contains high concentrations of chloride …

Chemical reactivity, kinetics, degradation pathways and mechanisms, and ecotoxicity of the
oxidation of 1-vinyl-3-ethylimidazolium bromide ([VEIm] Br), the most common alternative to …