Cyanation: a photochemical approach and applications in organic synthesis

RI Patel, S Sharma, A Sharma - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Photoredox chemistry has emerged as an efficient tool in catalyzing organic reactions as it
utilizes light as an energy source without any external initiator or reagent. The cyanide group …

Ultrasound-promoted Brønsted acid ionic liquid-catalyzed hydrothiocyanation of activated alkynes under minimal solvent conditions

C Wu, LH Lu, AZ Peng, GK Jia, C Peng, Z Cao… - Green …, 2018 - pubs.rsc.org
By using water as the hydrogen source, an eco-friendly and practical protocol for the
synthesis of Z-vinyl thiocyanates through ultrasound-promoted Brønsted acid ionic liquid …

Recent advances in the synthesis and reactivity of isothiazoles

A De Oliveira Silva, J McQuade… - Advanced Synthesis & …, 2019 - Wiley Online Library
Isothiazoles represent an important class of five‐membered sulfur heterocycles that are
widely utilized in medicinal chemistry and organic synthesis due to the unique properties of …

Visible light-induced thiocyanation of enaminone C–H bond to access polyfunctionalized alkenes and thiocyano chromones

Y Gao, Y Liu, JP Wan - The Journal of Organic Chemistry, 2019 - ACS Publications
The visible light induced C–H bond thiocyanation on the α-site of tertiary enaminones has
been realized under metal-free, photocatalytic conditions in the presence of Rose Bengal …

Photocatalytic C–H Thiocyanation of NH2-Enaminones and the Tunable Synthetic Routes to 2-Aminothiazoles and 2-Thiazolinones

J Zeng, JP Wan, Y Liu - The Journal of Organic Chemistry, 2022 - ACS Publications
Visible light photocatalytic reactions of NH2-enaminones and ammonium thiocyanate for
chemoselective α-C–H thiocyanation have been realized for the first time, providing a …

Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature

LH Lu, SJ Zhou, WB He, W Xia, P Chen, X Yu… - Organic & …, 2018 - pubs.rsc.org
A simple and practical method for the synthesis of alkenyl dithiocyanates and alkenyl
diselenocyanates has been developed via stereoselective difunctionalization of alkynes with …

Temperature-controlled chalcogenation and chalcogenocyanation of imidazopyridines in water under transition metal-free conditions

YS Zhu, Y Xue, W Liu, X Zhu, XQ Hao… - The Journal of Organic …, 2020 - ACS Publications
A sustainable and transition metal-free approach for C3 chalcogenation and
chalcogenocyanation of imidazopyridines with KXCN (X= S or Se) has been developed …

Expeditious Access to Spiro-Fused 2,5-Cyclohexadienones via Thio(seleno)cyanative ipso-Cyclization

C Raji Reddy, U Ajaykumar… - The Journal of Organic …, 2020 - ACS Publications
A facile oxidative dearomatization of N-(p-methoxyaryl) propiolamides has been established
for the synthesis of spiro-fused 2, 5-cyclohexadienone frameworks via thio (seleno) …

A nickel-catalyzed anti-carbometallative cyclization of alkyne–azides with organoboronic acids: synthesis of 2, 3-diarylquinolines

GR Kumar, R Kumar, M Rajesh… - Chemical …, 2018 - pubs.rsc.org
An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido
phenyl propargyl alcohols with aryl boronic acids is achieved using Ni (acac) 2 as the …

PIDA-mediated α-C–H functionalization of enaminones: the synthesis of thiocyano enaminones and chromones in water

Z Yang, L Hu, T Cao, L An, L Li, T Yang… - New Journal of …, 2019 - pubs.rsc.org
Herein, an efficient, metal-free process for the α-C–H thiocyanation of enaminones was
developed using PhI (OAc) 2 as an oxidant at room temperature in an aqueous medium …