Recent advances in flame retardant polymers via thiol-ene click chemistry

E Çakmakçı - Journal of Macromolecular Science, Part A, 2023 - Taylor & Francis
Within the toolbox of click chemistry, the utilization of thiol-ene reactions for polymer
synthesis and modification is a current area of intense attention. Thiol-ene click reactions are …

New Horizon in Phospha-Michael Reaction: Ultrafast Double Addition of P–H Bond-Bearing Nucleophiles to Electron-Deficient Triple Bonds and Its Use for Functional …

G Sagdic, O Daglar, E Cakmakci, V Findik… - …, 2023 - ACS Publications
In this work, a novel, straightforward, robust, fast, and organocatalyst-mediated phospha-
Michael reaction (OCPMR) was developed for the addition of phosphorus nucleophiles to …

Amino-yne reaction: An exquisite method for polymer-polymer conjugation and post-polymerization modification

E Akar, S Luleburgaz, US Gunay, V Kumbaraci… - European Polymer …, 2023 - Elsevier
The amino-yne reaction, which performs between an electron-deficient alkyne and an
amine, has been shown to proceed with high efficiency under mild conditions and has …

Fully Biobased Self-Healing and Recyclable Covalent Adaptable Networks Prepared via a Catalyst-Free Aza-Michael Reaction

SS Kashyap, K Borah… - ACS Applied Polymer …, 2024 - ACS Publications
In the present scenario, petroleum resource-based thermoset materials have become an
environmental threat due to their permanent cross-linked structure that limits their …

Fusion of immiscible covalent adaptable networks rooted in Enamine-One and β-Amino ester bonds with robust mechanically and excellent re-processing properties

X Guo, F Gao, F Chen, L Chen, X Gao… - Chemical Engineering …, 2024 - Elsevier
Covalent adaptable networks (CANs) are widely used because of their outstanding
mechanical properties and reprocessibility. However, these materials can only be recycled …

Imide-Yne Click Polymerization: A New and Versatile Tool for the Toolbox of X-Yne Click Polymerization

O Aslanturk, G Sagdic, E Cakmakci, H Durmaz… - Polymer …, 2024 - pubs.rsc.org
The Michael reaction, a cornerstone in organic chemistry, continues to revolutionize the field
with its unparalleled versatility in forming carbon-carbon, carbon-oxygen, carbon-nitrogen …

Synthesis of dynamic polymers by amino-yne click reaction using multifunctional amine

F Chen, F Gao, X Guo, Y Chen, X Gao… - Progress in Organic …, 2024 - Elsevier
Covalent adaptable networks (CANs) have become sustainable alternatives to traditional
thermosetting materials due to their powerful reprocessing and rearrangement capabilities …

One‐Step Solvent‐Free Synthesis of Dimer Diamine‐Based Autocatalytic Polyol for the Preparation of Polyurethane Foams

B Nasuhoglu, E Çakmakçi… - Macromolecular …, 2024 - Wiley Online Library
Herein, this work reports the facile synthesis of a dimer diamine‐based autocatalytic polyol
(ACP) and its use in polyurethane foam preparation. The ACP, namely TETRAOL is …