Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications

J Zhang, Y Huang, G Li, Y Wei - Coordination Chemistry Reviews, 2019 - Elsevier
Polyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo,
W, V, etc. early transition metal ions in their highest oxidation states, have received …

Polyoxometalates: formation, structures, principal properties, main deposition methods and application in sensing

M Ammam - Journal of Materials Chemistry A, 2013 - pubs.rsc.org
Today, sensing represents one of the key topics in current science and technology.
Polyoxometalates (POMs), which are defined as early transition metal clusters, are …

Polymeric thin films for organic electronics: Properties and adaptive structures

S Cataldo, B Pignataro - Materials, 2013 - mdpi.com
This review deals with the correlation between morphology, structure and performance of
organic electronic devices including thin film transistors and solar cells. In particular, we …

Nanometer-size polyoxometalate anions adsorb strongly on neutral soft surfaces

B Naskar, O Diat, V Nardello-Rataj… - The Journal of Physical …, 2015 - ACS Publications
Polyoxometalates (POMs) are nanometric metal–oxide anions with unique chemical and
physical properties. During the past decade, significant efforts have been made to give …

Towards polyoxometalate‐cluster‐based nano‐electronics

L Vilà‐Nadal, SG Mitchell, S Markov… - … A European Journal, 2013 - Wiley Online Library
We explore the concept that the incorporation of polyoxometalates (POMs) into
complementary metal oxide semiconductor (CMOS) technologies could offer a …

[PDF][PDF] 2.10-Polyoxometalates: Synthesis and Structure–From Building Blocks to Emergent Materials

M Hutin, MH Rosnes, DL Long, L Cronin - … Inorganic Chemistry II, 2013 - Citeseer
Polyoxometalates (POMs) can be described as metal-oxo cluster anions, which cover a
large range of structures in terms of size and elemental composition. The terminal oxo …

Are keggin's POMs charged nanocolloids or multicharged anions?

A Malinenko, A Jonchère, L Girard… - Langmuir, 2018 - ACS Publications
Owing to their multiple charges and their nanometric size, polyoxometalates (POMs) are at
the frontier between ions and charged colloids. We investigated here the effect of POM …

Self-Assembly of Short Chain Poly-N-isopropylacrylamid Induced by Superchaotropic Keggin Polyoxometalates: From Globules to Sheets

T Buchecker, P Schmid, I Grillo, S Prévost… - Journal of the …, 2019 - ACS Publications
We show here for the first time that short chain poly (N-isopropylacrylamide)(PNIPAM), one
of the most famous thermoresponsive polymers, self-assembles in water to form (i) discrete …

Microwave-Assisted Synthesis of Tris-Anderson Polyoxometalates for Facile CO2 Cycloaddition

WD Yu, Y Zhang, YY Han, B Li, S Shao… - Inorganic …, 2021 - ACS Publications
Four new tris-Anderson polyoxometalates (POMs),(NH4) 4 [ZnMo6O18 (C4H8NO3)(OH) 3]·
4H2O (1),(NH4) 4 [CuMo6O18 (C4H8NO3)(OH) 3]· 4H2O (2),(TBA) 3 (NH4)[ZnMo6O17 …

Charge transport through redox active [H 7 P 8 W 48 O 184] 33− polyoxometalates self-assembled onto gold surfaces and gold nanodots

K Dalla Francesca, S Lenfant, M Laurans, F Volatron… - Nanoscale, 2019 - pubs.rsc.org
Polyoxometalates (POMs) are redox-active molecular oxides, which attract growing interest
for their integration into nano-devices, such as high-density data storage non-volatile …