Giant molecules are a new class of precise macromolecules whose constructing blocks are
molecular nanoparticles, such as polyhedral oligomeric silsesquioxane (POSS), fullerene …

Linear polymers with the same monomer units and different molecular weights form miscible
blends considered to be single polymers, but the situation changes if one is hyperbranched …

Dendrimers are a wide group of chemical compounds that are still being studied extensively.
New dendrimer cores are sought to improve their physicochemical properties. We present …

A series of carbosilane dendrimers of the 4th, 6th, and 7th generations with a terminal
trimethylsilylsiloxane layer was synthesized. Theoretical models of these dendrimers were …

dimensional architectured polymers, for example, giant molecules, present distinct dynamics
from chain-like polymers and are coarse-grained as soft-clusters. There is a critical number …

This paper presents a synthesis of new boron-substituted carborane-carbosilane
dendrimers of the zero (G 0-4 cages), first (G 1-8 cages), third (G 3-32 cages), and fifth (G 5 …

Functionalizing the internal structure of classical dendrimers is a new way of tailoring their
properties. Using atomistic molecular dynamics simulations, we investigate the rheological …

Non-functional derivatives of polymethylsilsesquioxane (PMSSQ) dendrimers of first to fourth
generation were synthesized for the first time using combination of divergent and convergent …

Acting as soft-nanoparticles, series of microgels are microemulsion polymerized and
investigated for their dynamics in the melt state. Each series is kept at the same average …

A methodology for synthesizing a wide range of dumbbell‐shaped, graft and bottlebrush
polymers with all‐siloxane nature (without carbosilane linkers) is suggested. These …