Deep eutectic solvents: A review of fundamentals and applications

BB Hansen, S Spittle, B Chen, D Poe, Y Zhang… - Chemical …, 2020 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by
significant depressions in melting points compared to those of the neat constituent …

NMR relaxometry accessing the relaxation spectrum in molecular glass formers

M Becher, A Lichtinger, R Minikejew, M Vogel… - International Journal of …, 2022 - mdpi.com
It is a longstanding question whether universality or specificity characterize the molecular
dynamics underlying the glass transition of liquids. In particular, there is an ongoing debate …

Nature of dielectric response of phenyl alcohols

M Tarnacka, A Czaderna-Lekka… - The Journal of …, 2023 - ACS Publications
Phenyl alcohols (PhAs) are an interesting class of materials, for which the dielectric
response reveals only the presence of single prominent Debye-like (D) relaxation …

Slow rheological mode in glycerol and glycerol–water mixtures

MH Jensen, C Gainaru, C Alba-Simionesco… - Physical Chemistry …, 2018 - pubs.rsc.org
Glycerol–water mixtures were studied at molar concentrations ranging from xgly= 1 (neat
glycerol) to xgly= 0.3 using shear mechanical spectroscopy. We observed a low frequency …

Influence of molecular architecture on the dynamics of H-bonded supramolecular structures in phenyl-propanols

T Böhmer, JP Gabriel, T Richter, F Pabst… - The Journal of …, 2019 - ACS Publications
Relaxation behavior of monohydroxy alcohols (monoalcohols) in broadband dielectric
spectroscopy (BDS) is usually dominated by the Debye process. This process is regarded as …

Mesoscale organization and dynamics in binary ionic liquid mixtures

T Cosby, U Kapoor, JK Shah… - The journal of physical …, 2019 - ACS Publications
The impact of mesoscale organization on dynamics and ion transport in binary ionic liquid
mixtures is investigated by broad-band dielectric spectroscopy, dynamic-mechanical …

Hydrogen Bonding Exchange and Supramolecular Dynamics of Monohydroxy Alcohols

S Cheng, S Patil, S Cheng - Physical Review Letters, 2024 - APS
We unravel hydrogen bonding dynamics and their relationship with supramolecular
relaxations of monohydroxy alcohols (MAs) at intermediate times. The rheological modulus …

[HTML][HTML] Revealing complex relaxation behavior of monohydroxy alcohols in a series of octanol isomers

T Böhmer, T Richter, JP Gabriel, R Zeißler… - The Journal of …, 2023 - pubs.aip.org
We investigate the reorientation dynamics of four octanol isomers with very different
characteristics regarding the formation of hydrogen-bonded structures by means of photon …

Interplay between structural static and dynamical parameters as a key factor to understand peculiar behaviour of associated liquids

K Jurkiewicz, S Kołodziej, B Hachuła… - Journal of Molecular …, 2020 - Elsevier
In this article, we have addressed fundamental relationships between the chemical structure,
intermolecular order, degree of the association and the dynamical properties, including the …

Isomeric effects in structure formation and dielectric dynamics of different octanols

J Bolle, SP Bierwirth, M Požar, A Perera… - Physical Chemistry …, 2021 - pubs.rsc.org
The understanding of the microstructure of associated liquids promoted by hydrogen-
bonding and constrained by steric hindrance is highly relevant in chemistry, physics, biology …