Synthesis, characterization and properties of a novel fluorinated polyurethane
Z Ge, X Zhang, J Dai, W Li, Y Luo - European Polymer Journal, 2009 - Elsevier
A novel fluorinated polyurethane (FPU) was prepared by fluorinated polyether glycol (PTMG-
g-HFP) as a soft segment, 1, 6-hexamethylene diisocyanate (HDI) or toluene diisocyanate …
g-HFP) as a soft segment, 1, 6-hexamethylene diisocyanate (HDI) or toluene diisocyanate …
Absolute rates of intermolecular carbon− hydrogen abstraction reactions by fluorinated radicals
AB Shtarev, F Tian, WR Dolbier… - Journal of the American …, 1999 - ACS Publications
Using competition kinetic methodology, absolute rate constants for bimolecular hydrogen
abstraction from a variety of organic substrates in solution have been obtained for the n …
abstraction from a variety of organic substrates in solution have been obtained for the n …
Synthesis of internal fluorinated alkenes via facile aryloxylation of substituted phenols with aryl trifluorovinyl ethers
JD Moody, D VanDerveer, DW Smith Jr… - Organic & Biomolecular …, 2011 - pubs.rsc.org
Nucleophilic addition–elimination of ortho-or para-substituted phenols to aryl trifluorovinyl
ethers (TFVEs) in N, N-dimethylformamide was studied. Using sodium hydride as a base …
ethers (TFVEs) in N, N-dimethylformamide was studied. Using sodium hydride as a base …
Systematic study of nucleophile additions to 1-bromo-4-(trifluorovinyloxy) benzene: A versatile intermediate toward fluorinated ethers of synthetic interest
The nature of the structural configuration of fluorinated ethers has been widespread as a
crucial component for improving high performance polymers, industrial agrochemicals, and …
crucial component for improving high performance polymers, industrial agrochemicals, and …
Reactivity study of 1, 1, 2, 4, 4, 5, 7, 7, 8, 8, 9, 9, 9-tridecafluoro-5-trifluoromethyl-3, 6-dioxanon-1-ene in nucleophilic reactions: fluorination properties of secondary …
I Dlouhá, J Kvičala, O Paleta - Journal of fluorine chemistry, 2002 - Elsevier
A series of nucleophiles was reacted with 1, 1, 2, 4, 4, 5, 7, 7, 8, 8, 9, 9, 9-tridecafluoro-5-
trifluoromethyl-3, 6-dioxanon-1-ene (1) as a representative of perfluoro (alkyl vinyl ethers) …
trifluoromethyl-3, 6-dioxanon-1-ene (1) as a representative of perfluoro (alkyl vinyl ethers) …
Novel amphiphilic fluoroalkylated derivatives of xylitol, d-glucose and d-galactose for medical applications: hemocompatibility and co-emulsifying properties
O Paleta, I Dlouhá, R Kaplánek, K Kefurt… - Carbohydrate …, 2002 - Elsevier
1-O-(4, 4, 5, 5, 6, 6, 7, 7, 8, 8, 9, 9, 9-Tridecafluorononyl) xylitol 6 was synthesized as a novel
standard compound for the assessment of hemocompatibility and co-emulsifying properties …
standard compound for the assessment of hemocompatibility and co-emulsifying properties …
Radical addition reactions of fluorinated species. Part 7. Highly selective two-step synthesis of 1-(polyfluoroalkyl) ethane-1, 2-diols; regioselectivity of the additions of …
V Cı́rkva, O Paleta - Journal of fluorine chemistry, 1999 - Elsevier
The two-step synthesis of the diols is based on the radical addition of 2, 2-dimethyl-1, 3-
dioxolane (1), a protected ethane-1, 2-diol, to perfluoroalk-1-enes RF–CF CF2 (RF CF3 …
dioxolane (1), a protected ethane-1, 2-diol, to perfluoroalk-1-enes RF–CF CF2 (RF CF3 …
Absolute rate constants for some hydrogen atom abstraction reactions by a primary fluoroalkyl radical in water
L Zhang, J Cradlebaugh, G Litwinienko… - Organic & …, 2004 - pubs.rsc.org
A combination of laser flash photolysis and competitive kinetic methods have been used to
measure the absolute bimolecular rate constants for hydrogen atom abstraction in water …
measure the absolute bimolecular rate constants for hydrogen atom abstraction in water …
Synthesis and characterization of a new fluorinated polyether glycol prepared by radical grafting of hexafluoropropylene onto polytetramethylene glycol
Z Ge, X Zhang, J Dai - European polymer journal, 2006 - Elsevier
A new fluorinated polyether glycol (PTMG-g-HFP) was prepared by radical grafting of
hexafluoropropylene (HFP) onto polytetramethylene glycol (PTMG) in the presence of …
hexafluoropropylene (HFP) onto polytetramethylene glycol (PTMG) in the presence of …
Radical addition reactions of fluorinated species. Part 8. Regioselectivity of radical additions to perfluoroalkylethylenes and quantum chemical calculations. Highly …
V Cı́rkva, S BoÈhm, O Paleta - Journal of Fluorine Chemistry, 2000 - Elsevier
Perfluoroalkylethylenes RF–CH CH2 (RF= C4F9, C6F13, C8F17) added easily
nucleophilic radicals generated from alkanols, oxolane and 2, 2-dimethyl-1, 3-dioxolane …
nucleophilic radicals generated from alkanols, oxolane and 2, 2-dimethyl-1, 3-dioxolane …